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(E)-2-[4-(Diethyl­amino)­styr­yl]-1-methyl­pyridinium 4-meth­oxy­benzene­sulfonate monohydrate

In the cation of the title compound, C(18)H(23)N(2) (+)·C(7)H(7)O(4)S(−)·H(2)O, one ethyl group of the diethyl­amino unit is disordered over two sets of sites in a 0.665 (6):0.335 (6) ratio. The styrylpyridinium unit is nearly planar, with a dihedral angle between the pyridinium and benzene rings of...

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Autores principales: Chantrapromma, Suchada, Kaewmanee, Narissara, Boonnak, Nawong, Anantapong, Teerasak, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435741/
https://www.ncbi.nlm.nih.gov/pubmed/22969612
http://dx.doi.org/10.1107/S1600536812035258
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author Chantrapromma, Suchada
Kaewmanee, Narissara
Boonnak, Nawong
Anantapong, Teerasak
Fun, Hoong-Kun
author_facet Chantrapromma, Suchada
Kaewmanee, Narissara
Boonnak, Nawong
Anantapong, Teerasak
Fun, Hoong-Kun
author_sort Chantrapromma, Suchada
collection PubMed
description In the cation of the title compound, C(18)H(23)N(2) (+)·C(7)H(7)O(4)S(−)·H(2)O, one ethyl group of the diethyl­amino unit is disordered over two sets of sites in a 0.665 (6):0.335 (6) ratio. The styrylpyridinium unit is nearly planar, with a dihedral angle between the pyridinium and benzene rings of 4.27 (8)°. In the crystal, the anion ring is almost perpendicular to the aromatic rings of the cation; the sulfonate-substituted benzene ring forms dihedral angles of 89.60 (8) and 89.37 (8)°, respectively, with the pyridinium and benzene rings of the cation. In the crystal, the three components are linked into a three-dimensional network by O—H⋯O and C—H⋯O hydrogen bonds. π–π inter­actions with centroid–centroid distances of 3.6999 (9) and 3.7106 (9) Å are also present.
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spelling pubmed-34357412012-09-11 (E)-2-[4-(Diethyl­amino)­styr­yl]-1-methyl­pyridinium 4-meth­oxy­benzene­sulfonate monohydrate Chantrapromma, Suchada Kaewmanee, Narissara Boonnak, Nawong Anantapong, Teerasak Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the cation of the title compound, C(18)H(23)N(2) (+)·C(7)H(7)O(4)S(−)·H(2)O, one ethyl group of the diethyl­amino unit is disordered over two sets of sites in a 0.665 (6):0.335 (6) ratio. The styrylpyridinium unit is nearly planar, with a dihedral angle between the pyridinium and benzene rings of 4.27 (8)°. In the crystal, the anion ring is almost perpendicular to the aromatic rings of the cation; the sulfonate-substituted benzene ring forms dihedral angles of 89.60 (8) and 89.37 (8)°, respectively, with the pyridinium and benzene rings of the cation. In the crystal, the three components are linked into a three-dimensional network by O—H⋯O and C—H⋯O hydrogen bonds. π–π inter­actions with centroid–centroid distances of 3.6999 (9) and 3.7106 (9) Å are also present. International Union of Crystallography 2012-08-15 /pmc/articles/PMC3435741/ /pubmed/22969612 http://dx.doi.org/10.1107/S1600536812035258 Text en © Chantrapromma et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chantrapromma, Suchada
Kaewmanee, Narissara
Boonnak, Nawong
Anantapong, Teerasak
Fun, Hoong-Kun
(E)-2-[4-(Diethyl­amino)­styr­yl]-1-methyl­pyridinium 4-meth­oxy­benzene­sulfonate monohydrate
title (E)-2-[4-(Diethyl­amino)­styr­yl]-1-methyl­pyridinium 4-meth­oxy­benzene­sulfonate monohydrate
title_full (E)-2-[4-(Diethyl­amino)­styr­yl]-1-methyl­pyridinium 4-meth­oxy­benzene­sulfonate monohydrate
title_fullStr (E)-2-[4-(Diethyl­amino)­styr­yl]-1-methyl­pyridinium 4-meth­oxy­benzene­sulfonate monohydrate
title_full_unstemmed (E)-2-[4-(Diethyl­amino)­styr­yl]-1-methyl­pyridinium 4-meth­oxy­benzene­sulfonate monohydrate
title_short (E)-2-[4-(Diethyl­amino)­styr­yl]-1-methyl­pyridinium 4-meth­oxy­benzene­sulfonate monohydrate
title_sort (e)-2-[4-(diethyl­amino)­styr­yl]-1-methyl­pyridinium 4-meth­oxy­benzene­sulfonate monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435741/
https://www.ncbi.nlm.nih.gov/pubmed/22969612
http://dx.doi.org/10.1107/S1600536812035258
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