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(E)-2-[4-(Diethylamino)styryl]-1-methylpyridinium 4-methoxybenzenesulfonate monohydrate
In the cation of the title compound, C(18)H(23)N(2) (+)·C(7)H(7)O(4)S(−)·H(2)O, one ethyl group of the diethylamino unit is disordered over two sets of sites in a 0.665 (6):0.335 (6) ratio. The styrylpyridinium unit is nearly planar, with a dihedral angle between the pyridinium and benzene rings of...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435741/ https://www.ncbi.nlm.nih.gov/pubmed/22969612 http://dx.doi.org/10.1107/S1600536812035258 |
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author | Chantrapromma, Suchada Kaewmanee, Narissara Boonnak, Nawong Anantapong, Teerasak Fun, Hoong-Kun |
author_facet | Chantrapromma, Suchada Kaewmanee, Narissara Boonnak, Nawong Anantapong, Teerasak Fun, Hoong-Kun |
author_sort | Chantrapromma, Suchada |
collection | PubMed |
description | In the cation of the title compound, C(18)H(23)N(2) (+)·C(7)H(7)O(4)S(−)·H(2)O, one ethyl group of the diethylamino unit is disordered over two sets of sites in a 0.665 (6):0.335 (6) ratio. The styrylpyridinium unit is nearly planar, with a dihedral angle between the pyridinium and benzene rings of 4.27 (8)°. In the crystal, the anion ring is almost perpendicular to the aromatic rings of the cation; the sulfonate-substituted benzene ring forms dihedral angles of 89.60 (8) and 89.37 (8)°, respectively, with the pyridinium and benzene rings of the cation. In the crystal, the three components are linked into a three-dimensional network by O—H⋯O and C—H⋯O hydrogen bonds. π–π interactions with centroid–centroid distances of 3.6999 (9) and 3.7106 (9) Å are also present. |
format | Online Article Text |
id | pubmed-3435741 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34357412012-09-11 (E)-2-[4-(Diethylamino)styryl]-1-methylpyridinium 4-methoxybenzenesulfonate monohydrate Chantrapromma, Suchada Kaewmanee, Narissara Boonnak, Nawong Anantapong, Teerasak Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the cation of the title compound, C(18)H(23)N(2) (+)·C(7)H(7)O(4)S(−)·H(2)O, one ethyl group of the diethylamino unit is disordered over two sets of sites in a 0.665 (6):0.335 (6) ratio. The styrylpyridinium unit is nearly planar, with a dihedral angle between the pyridinium and benzene rings of 4.27 (8)°. In the crystal, the anion ring is almost perpendicular to the aromatic rings of the cation; the sulfonate-substituted benzene ring forms dihedral angles of 89.60 (8) and 89.37 (8)°, respectively, with the pyridinium and benzene rings of the cation. In the crystal, the three components are linked into a three-dimensional network by O—H⋯O and C—H⋯O hydrogen bonds. π–π interactions with centroid–centroid distances of 3.6999 (9) and 3.7106 (9) Å are also present. International Union of Crystallography 2012-08-15 /pmc/articles/PMC3435741/ /pubmed/22969612 http://dx.doi.org/10.1107/S1600536812035258 Text en © Chantrapromma et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Chantrapromma, Suchada Kaewmanee, Narissara Boonnak, Nawong Anantapong, Teerasak Fun, Hoong-Kun (E)-2-[4-(Diethylamino)styryl]-1-methylpyridinium 4-methoxybenzenesulfonate monohydrate |
title | (E)-2-[4-(Diethylamino)styryl]-1-methylpyridinium 4-methoxybenzenesulfonate monohydrate |
title_full | (E)-2-[4-(Diethylamino)styryl]-1-methylpyridinium 4-methoxybenzenesulfonate monohydrate |
title_fullStr | (E)-2-[4-(Diethylamino)styryl]-1-methylpyridinium 4-methoxybenzenesulfonate monohydrate |
title_full_unstemmed | (E)-2-[4-(Diethylamino)styryl]-1-methylpyridinium 4-methoxybenzenesulfonate monohydrate |
title_short | (E)-2-[4-(Diethylamino)styryl]-1-methylpyridinium 4-methoxybenzenesulfonate monohydrate |
title_sort | (e)-2-[4-(diethylamino)styryl]-1-methylpyridinium 4-methoxybenzenesulfonate monohydrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435741/ https://www.ncbi.nlm.nih.gov/pubmed/22969612 http://dx.doi.org/10.1107/S1600536812035258 |
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