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4-Carbamoylpyridin-1-ium 2,2,2-trichloroacetate
In the asymmetric unit of the title salt, C(6)H(7)N(2)O(+)·C(2)Cl(3)O(2) (−), there are two crystallographic independent ion pairs. The amide groups of the 4-carbamoylpyridin-1-ium ions are slightly twisted out of the plane of the aromatic ring with C—C—C—N torsion angles of 8.8 (9)° and 4.6 (8)°. I...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435745/ https://www.ncbi.nlm.nih.gov/pubmed/22969616 http://dx.doi.org/10.1107/S1600536812035507 |
Sumario: | In the asymmetric unit of the title salt, C(6)H(7)N(2)O(+)·C(2)Cl(3)O(2) (−), there are two crystallographic independent ion pairs. The amide groups of the 4-carbamoylpyridin-1-ium ions are slightly twisted out of the plane of the aromatic ring with C—C—C—N torsion angles of 8.8 (9)° and 4.6 (8)°. In the crystal, the 4-carbamoylpyridin-1-ium ion is N—H⋯O hydrogen bonded to the trichloroacetate ion via the pyridinium unit and amide group. Layers parallel to the ac plane are formed due to the N—H⋯O hydrogen bonding of the adjacent amide groups of 4-carbamoylpyridin-1-ium ions. Weak C—H⋯O interactions also occur. |
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