N,N′-(4,5-Dimethyl-1,2-phenyl­ene)bis­(pyridine-2-carboxamide)

In the title compound, C(20)H(18)N(4)O(2), the dihedral angles between the central benzene ring and the pyridine rings are 57.55 (6) and 22.05 (8)°. The mol­ecular conformation is stabilized by intra­molecular N—H⋯N inter­actions and in the crystal structure an inter­molecular asymmetric cyclic hydr...

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Detalles Bibliográficos
Autores principales: Van der Berg, Phillipus C. W., Visser, Hendrik G., Roodt, Andreas, Muller, Theunis J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435751/
https://www.ncbi.nlm.nih.gov/pubmed/22969622
http://dx.doi.org/10.1107/S1600536812035064
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author Van der Berg, Phillipus C. W.
Visser, Hendrik G.
Roodt, Andreas
Muller, Theunis J.
author_facet Van der Berg, Phillipus C. W.
Visser, Hendrik G.
Roodt, Andreas
Muller, Theunis J.
author_sort Van der Berg, Phillipus C. W.
collection PubMed
description In the title compound, C(20)H(18)N(4)O(2), the dihedral angles between the central benzene ring and the pyridine rings are 57.55 (6) and 22.05 (8)°. The mol­ecular conformation is stabilized by intra­molecular N—H⋯N inter­actions and in the crystal structure an inter­molecular asymmetric cyclic hydrogen-bonding association involving both amide N—H donors and a common amide O-atom acceptor gives a chain extending along the c axis.
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spelling pubmed-34357512012-09-11 N,N′-(4,5-Dimethyl-1,2-phenyl­ene)bis­(pyridine-2-carboxamide) Van der Berg, Phillipus C. W. Visser, Hendrik G. Roodt, Andreas Muller, Theunis J. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(18)N(4)O(2), the dihedral angles between the central benzene ring and the pyridine rings are 57.55 (6) and 22.05 (8)°. The mol­ecular conformation is stabilized by intra­molecular N—H⋯N inter­actions and in the crystal structure an inter­molecular asymmetric cyclic hydrogen-bonding association involving both amide N—H donors and a common amide O-atom acceptor gives a chain extending along the c axis. International Union of Crystallography 2012-08-23 /pmc/articles/PMC3435751/ /pubmed/22969622 http://dx.doi.org/10.1107/S1600536812035064 Text en © Van der Berg et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Van der Berg, Phillipus C. W.
Visser, Hendrik G.
Roodt, Andreas
Muller, Theunis J.
N,N′-(4,5-Dimethyl-1,2-phenyl­ene)bis­(pyridine-2-carboxamide)
title N,N′-(4,5-Dimethyl-1,2-phenyl­ene)bis­(pyridine-2-carboxamide)
title_full N,N′-(4,5-Dimethyl-1,2-phenyl­ene)bis­(pyridine-2-carboxamide)
title_fullStr N,N′-(4,5-Dimethyl-1,2-phenyl­ene)bis­(pyridine-2-carboxamide)
title_full_unstemmed N,N′-(4,5-Dimethyl-1,2-phenyl­ene)bis­(pyridine-2-carboxamide)
title_short N,N′-(4,5-Dimethyl-1,2-phenyl­ene)bis­(pyridine-2-carboxamide)
title_sort n,n′-(4,5-dimethyl-1,2-phenyl­ene)bis­(pyridine-2-carboxamide)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435751/
https://www.ncbi.nlm.nih.gov/pubmed/22969622
http://dx.doi.org/10.1107/S1600536812035064
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AT visserhendrikg nn45dimethyl12phenylenebispyridine2carboxamide
AT roodtandreas nn45dimethyl12phenylenebispyridine2carboxamide
AT mullertheunisj nn45dimethyl12phenylenebispyridine2carboxamide

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