(1E,2E)-1,2-Bis(2,3-dihydro-1H-inden-1-yl­idene)hydrazine

In the title compound, C(18)H(16)N(2), there are two independent half-mol­ecules (A and B) in the asymmetric unit, each mol­ecule being completed by an inversion center situated in the mid-point of the central N—N bond. The mol­ecules themselves therefore are essentially planar with r.m.s. deviation...

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Detalles Bibliográficos
Autores principales: Imhof, Wolfgang, Wunderle, Joachim
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435753/
https://www.ncbi.nlm.nih.gov/pubmed/22969624
http://dx.doi.org/10.1107/S160053681203560X
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author Imhof, Wolfgang
Wunderle, Joachim
author_facet Imhof, Wolfgang
Wunderle, Joachim
author_sort Imhof, Wolfgang
collection PubMed
description In the title compound, C(18)H(16)N(2), there are two independent half-mol­ecules (A and B) in the asymmetric unit, each mol­ecule being completed by an inversion center situated in the mid-point of the central N—N bond. The mol­ecules themselves therefore are essentially planar with r.m.s. deviations of 0.015 (1) and 0.020 (1) Å, respectively. In the crystal, mol­ecules are connected via C—H⋯π inter­actions in which only type B mol­ecules are donors, while both A and B mol­ecules act as acceptors. As a result, type B mol­ecules are linked into infinite chains along b, which are inter­connected by molecules of type A.
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spelling pubmed-34357532012-09-11 (1E,2E)-1,2-Bis(2,3-dihydro-1H-inden-1-yl­idene)hydrazine Imhof, Wolfgang Wunderle, Joachim Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(16)N(2), there are two independent half-mol­ecules (A and B) in the asymmetric unit, each mol­ecule being completed by an inversion center situated in the mid-point of the central N—N bond. The mol­ecules themselves therefore are essentially planar with r.m.s. deviations of 0.015 (1) and 0.020 (1) Å, respectively. In the crystal, mol­ecules are connected via C—H⋯π inter­actions in which only type B mol­ecules are donors, while both A and B mol­ecules act as acceptors. As a result, type B mol­ecules are linked into infinite chains along b, which are inter­connected by molecules of type A. International Union of Crystallography 2012-08-23 /pmc/articles/PMC3435753/ /pubmed/22969624 http://dx.doi.org/10.1107/S160053681203560X Text en © Imhof and Wunderle 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Imhof, Wolfgang
Wunderle, Joachim
(1E,2E)-1,2-Bis(2,3-dihydro-1H-inden-1-yl­idene)hydrazine
title (1E,2E)-1,2-Bis(2,3-dihydro-1H-inden-1-yl­idene)hydrazine
title_full (1E,2E)-1,2-Bis(2,3-dihydro-1H-inden-1-yl­idene)hydrazine
title_fullStr (1E,2E)-1,2-Bis(2,3-dihydro-1H-inden-1-yl­idene)hydrazine
title_full_unstemmed (1E,2E)-1,2-Bis(2,3-dihydro-1H-inden-1-yl­idene)hydrazine
title_short (1E,2E)-1,2-Bis(2,3-dihydro-1H-inden-1-yl­idene)hydrazine
title_sort (1e,2e)-1,2-bis(2,3-dihydro-1h-inden-1-yl­idene)hydrazine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435753/
https://www.ncbi.nlm.nih.gov/pubmed/22969624
http://dx.doi.org/10.1107/S160053681203560X
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