Bis(2,6-dimethyl­pyridinium) dibromo­iodate bromide

In the title salt, 2C(7)H(10)N(+)·IBr(2) (−)·Br(−), each of the anions, viz. [IBr(2)](−) and Br(−), lie on a twofold axis. The IBr(2) (−) anion is almost linear, with a Br—I—Br angle of 178.25 (3)°. The cation is essentially planar (r.m.s. deviation = 0.0067 Å). In the crystal, each Br(−) anion link...

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Detalles Bibliográficos
Autores principales: Al-Far, Rawhi, Ali, Basem F., Haddad, Salim F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435755/
https://www.ncbi.nlm.nih.gov/pubmed/22969626
http://dx.doi.org/10.1107/S1600536812035702
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author Al-Far, Rawhi
Ali, Basem F.
Haddad, Salim F.
author_facet Al-Far, Rawhi
Ali, Basem F.
Haddad, Salim F.
author_sort Al-Far, Rawhi
collection PubMed
description In the title salt, 2C(7)H(10)N(+)·IBr(2) (−)·Br(−), each of the anions, viz. [IBr(2)](−) and Br(−), lie on a twofold axis. The IBr(2) (−) anion is almost linear, with a Br—I—Br angle of 178.25 (3)°. The cation is essentially planar (r.m.s. deviation = 0.0067 Å). In the crystal, each Br(−) anion links two cations via N—H⋯Br⋯H—N hydrogen-bonding inter­actions.
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spelling pubmed-34357552012-09-11 Bis(2,6-dimethyl­pyridinium) dibromo­iodate bromide Al-Far, Rawhi Ali, Basem F. Haddad, Salim F. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, 2C(7)H(10)N(+)·IBr(2) (−)·Br(−), each of the anions, viz. [IBr(2)](−) and Br(−), lie on a twofold axis. The IBr(2) (−) anion is almost linear, with a Br—I—Br angle of 178.25 (3)°. The cation is essentially planar (r.m.s. deviation = 0.0067 Å). In the crystal, each Br(−) anion links two cations via N—H⋯Br⋯H—N hydrogen-bonding inter­actions. International Union of Crystallography 2012-08-23 /pmc/articles/PMC3435755/ /pubmed/22969626 http://dx.doi.org/10.1107/S1600536812035702 Text en © Al-Far et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Al-Far, Rawhi
Ali, Basem F.
Haddad, Salim F.
Bis(2,6-dimethyl­pyridinium) dibromo­iodate bromide
title Bis(2,6-dimethyl­pyridinium) dibromo­iodate bromide
title_full Bis(2,6-dimethyl­pyridinium) dibromo­iodate bromide
title_fullStr Bis(2,6-dimethyl­pyridinium) dibromo­iodate bromide
title_full_unstemmed Bis(2,6-dimethyl­pyridinium) dibromo­iodate bromide
title_short Bis(2,6-dimethyl­pyridinium) dibromo­iodate bromide
title_sort bis(2,6-dimethyl­pyridinium) dibromo­iodate bromide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435755/
https://www.ncbi.nlm.nih.gov/pubmed/22969626
http://dx.doi.org/10.1107/S1600536812035702
work_keys_str_mv AT alfarrawhi bis26dimethylpyridiniumdibromoiodatebromide
AT alibasemf bis26dimethylpyridiniumdibromoiodatebromide
AT haddadsalimf bis26dimethylpyridiniumdibromoiodatebromide

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