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2,2′-{[2-(Pyridin-2-yl)-1,3-diazinane-1,3-diyl]bis(methylene)}diphenol
The title compound, C(23)H(25)N(3)O(2), was obtained as an intermediary in the preparation of non-symmetric tertiary diamines. The molecular structure presents T-shaped spatial form, in which the pyrimidine ring exhibits a chair conformation. The pyridyl ring is almost perpendicular to the phenyl...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435756/ https://www.ncbi.nlm.nih.gov/pubmed/22969627 http://dx.doi.org/10.1107/S1600536812035477 |
Sumario: | The title compound, C(23)H(25)N(3)O(2), was obtained as an intermediary in the preparation of non-symmetric tertiary diamines. The molecular structure presents T-shaped spatial form, in which the pyrimidine ring exhibits a chair conformation. The pyridyl ring is almost perpendicular to the phenyl rings with dihedral angles of 80.17 (8) and 76.03 (2)°. The phenol and amine groups are involved in two strong intramolecular O—H⋯N interactions. In the crystal, the molecules are stacked along [010]; however, no intermolecular interactions are observed. |
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