2,2′-{[2-(Pyridin-2-yl)-1,3-diazinane-1,3-diyl]bis(methylene)}diphenol

The title compound, C(23)H(25)N(3)O(2), was obtained as an inter­mediary in the preparation of non-symmetric tertiary diamines. The mol­ecular structure presents T-shaped spatial form, in which the pyrimidine ring exhibits a chair conformation. The pyridyl ring is almost perpendicular to the phenyl...

Descripción completa

Detalles Bibliográficos
Autores principales: Bortoluzzi, Adailton J., Terra, Geovana G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435756/
https://www.ncbi.nlm.nih.gov/pubmed/22969627
http://dx.doi.org/10.1107/S1600536812035477
_version_ 1782242585502285824
author Bortoluzzi, Adailton J.
Terra, Geovana G.
author_facet Bortoluzzi, Adailton J.
Terra, Geovana G.
author_sort Bortoluzzi, Adailton J.
collection PubMed
description The title compound, C(23)H(25)N(3)O(2), was obtained as an inter­mediary in the preparation of non-symmetric tertiary diamines. The mol­ecular structure presents T-shaped spatial form, in which the pyrimidine ring exhibits a chair conformation. The pyridyl ring is almost perpendicular to the phenyl rings with dihedral angles of 80.17 (8) and 76.03 (2)°. The phenol and amine groups are involved in two strong intra­molecular O—H⋯N inter­actions. In the crystal, the mol­ecules are stacked along [010]; however, no inter­molecular inter­actions are observed.
format Online
Article
Text
id pubmed-3435756
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-34357562012-09-11 2,2′-{[2-(Pyridin-2-yl)-1,3-diazinane-1,3-diyl]bis(methylene)}diphenol Bortoluzzi, Adailton J. Terra, Geovana G. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(23)H(25)N(3)O(2), was obtained as an inter­mediary in the preparation of non-symmetric tertiary diamines. The mol­ecular structure presents T-shaped spatial form, in which the pyrimidine ring exhibits a chair conformation. The pyridyl ring is almost perpendicular to the phenyl rings with dihedral angles of 80.17 (8) and 76.03 (2)°. The phenol and amine groups are involved in two strong intra­molecular O—H⋯N inter­actions. In the crystal, the mol­ecules are stacked along [010]; however, no inter­molecular inter­actions are observed. International Union of Crystallography 2012-08-23 /pmc/articles/PMC3435756/ /pubmed/22969627 http://dx.doi.org/10.1107/S1600536812035477 Text en © Bortoluzzi and Terra 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Bortoluzzi, Adailton J.
Terra, Geovana G.
2,2′-{[2-(Pyridin-2-yl)-1,3-diazinane-1,3-diyl]bis(methylene)}diphenol
title 2,2′-{[2-(Pyridin-2-yl)-1,3-diazinane-1,3-diyl]bis(methylene)}diphenol
title_full 2,2′-{[2-(Pyridin-2-yl)-1,3-diazinane-1,3-diyl]bis(methylene)}diphenol
title_fullStr 2,2′-{[2-(Pyridin-2-yl)-1,3-diazinane-1,3-diyl]bis(methylene)}diphenol
title_full_unstemmed 2,2′-{[2-(Pyridin-2-yl)-1,3-diazinane-1,3-diyl]bis(methylene)}diphenol
title_short 2,2′-{[2-(Pyridin-2-yl)-1,3-diazinane-1,3-diyl]bis(methylene)}diphenol
title_sort 2,2′-{[2-(pyridin-2-yl)-1,3-diazinane-1,3-diyl]bis(methylene)}diphenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435756/
https://www.ncbi.nlm.nih.gov/pubmed/22969627
http://dx.doi.org/10.1107/S1600536812035477
work_keys_str_mv AT bortoluzziadailtonj 222pyridin2yl13diazinane13diylbismethylenediphenol
AT terrageovanag 222pyridin2yl13diazinane13diylbismethylenediphenol

Ejemplares similares