Benzyl 3-[(E)-(furan-2-yl)methyl­idene]-2-methyldithio­carbazate

In the title compound, C(14)H(14)N(2)OS(2), the furan ring exhibits rotational disorder over two orientations, with an occupancy ratio of 0.508 (7):0.492 (7). The furan and phenyl rings form dihedral angles of 8.2 (6) (major occupancy component), 14.8 (6) (minor occupancy component) and 73.65 (9)°,...

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Detalles Bibliográficos
Autores principales: Dey, Benu K., Suarez, Sebastian, Ganguly, Biplab, Doctorovich, Fabio, Roy, Tapashi G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435764/
https://www.ncbi.nlm.nih.gov/pubmed/22969635
http://dx.doi.org/10.1107/S1600536812035520
Descripción
Sumario:In the title compound, C(14)H(14)N(2)OS(2), the furan ring exhibits rotational disorder over two orientations, with an occupancy ratio of 0.508 (7):0.492 (7). The furan and phenyl rings form dihedral angles of 8.2 (6) (major occupancy component), 14.8 (6) (minor occupancy component) and 73.65 (9)°, respectively, with the central residue (C(4)N(2)S(2)), indicating a twisted conformation for the mol­ecule. The methyl group and the thione S atom are syn and the conformation about the imine bond is E. In the crystal, C—H⋯π inter­actions involving the phenyl ring are observed.

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