N′-[(E)-2-Hy­droxy-5-iodo­benzyl­idene]-4-methyl­benzene­sulfono­hydrazide

In the title mol­ecule, C(14)H(13)IN(2)O(3)S, the dihedral angle between the planes of the benzene and toluene rings is 84.3 (3)°. The mol­ecule displays a trans conformation with respect to the C=N bond. There is an intra­molecular O—H⋯N hydrogen bond with the azomethine N atom as acceptor. In the...

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Detalles Bibliográficos
Autores principales: Ghorbanloo, Massomeh, Notash, Behrouz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435795/
https://www.ncbi.nlm.nih.gov/pubmed/22969641
http://dx.doi.org/10.1107/S1600536812035738
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author Ghorbanloo, Massomeh
Notash, Behrouz
author_facet Ghorbanloo, Massomeh
Notash, Behrouz
author_sort Ghorbanloo, Massomeh
collection PubMed
description In the title mol­ecule, C(14)H(13)IN(2)O(3)S, the dihedral angle between the planes of the benzene and toluene rings is 84.3 (3)°. The mol­ecule displays a trans conformation with respect to the C=N bond. There is an intra­molecular O—H⋯N hydrogen bond with the azomethine N atom as acceptor. In the crystal, N—H⋯O hydrogen bonds connect the mol­ecules into chains running along the b axis.
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spelling pubmed-34357952012-09-11 N′-[(E)-2-Hy­droxy-5-iodo­benzyl­idene]-4-methyl­benzene­sulfono­hydrazide Ghorbanloo, Massomeh Notash, Behrouz Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(14)H(13)IN(2)O(3)S, the dihedral angle between the planes of the benzene and toluene rings is 84.3 (3)°. The mol­ecule displays a trans conformation with respect to the C=N bond. There is an intra­molecular O—H⋯N hydrogen bond with the azomethine N atom as acceptor. In the crystal, N—H⋯O hydrogen bonds connect the mol­ecules into chains running along the b axis. International Union of Crystallography 2012-08-23 /pmc/articles/PMC3435795/ /pubmed/22969641 http://dx.doi.org/10.1107/S1600536812035738 Text en © Ghorbanloo and Notash 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ghorbanloo, Massomeh
Notash, Behrouz
N′-[(E)-2-Hy­droxy-5-iodo­benzyl­idene]-4-methyl­benzene­sulfono­hydrazide
title N′-[(E)-2-Hy­droxy-5-iodo­benzyl­idene]-4-methyl­benzene­sulfono­hydrazide
title_full N′-[(E)-2-Hy­droxy-5-iodo­benzyl­idene]-4-methyl­benzene­sulfono­hydrazide
title_fullStr N′-[(E)-2-Hy­droxy-5-iodo­benzyl­idene]-4-methyl­benzene­sulfono­hydrazide
title_full_unstemmed N′-[(E)-2-Hy­droxy-5-iodo­benzyl­idene]-4-methyl­benzene­sulfono­hydrazide
title_short N′-[(E)-2-Hy­droxy-5-iodo­benzyl­idene]-4-methyl­benzene­sulfono­hydrazide
title_sort n′-[(e)-2-hy­droxy-5-iodo­benzyl­idene]-4-methyl­benzene­sulfono­hydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435795/
https://www.ncbi.nlm.nih.gov/pubmed/22969641
http://dx.doi.org/10.1107/S1600536812035738
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