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(3′R)-3′-Benzyl-2′,3′-dihydro-1H-spiro[indole-3,1′-naphtho[2,3-c]pyrrole]-2,4′,9′-trione
In the title compound, C(26)H(18)N(2)O(3), the maximum deviations from planarity for the tetrahydro-1H-naphtho[2,3-c]pyrrole and indoline rings systems are 0.091 (1) and 0.012 (2) Å, respectively. These ring systems make a dihedral angle of 89.95 (6)° with each other and they make dihedral angles...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435804/ https://www.ncbi.nlm.nih.gov/pubmed/22969650 http://dx.doi.org/10.1107/S1600536812036227 |
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author | Sharma, Garima Kumar, S. Vasanth Wahab, Habibah A. Rosli, Mohd Mustaqim Fun, Hoong-Kun |
author_facet | Sharma, Garima Kumar, S. Vasanth Wahab, Habibah A. Rosli, Mohd Mustaqim Fun, Hoong-Kun |
author_sort | Sharma, Garima |
collection | PubMed |
description | In the title compound, C(26)H(18)N(2)O(3), the maximum deviations from planarity for the tetrahydro-1H-naphtho[2,3-c]pyrrole and indoline rings systems are 0.091 (1) and 0.012 (2) Å, respectively. These ring systems make a dihedral angle of 89.95 (6)° with each other and they make dihedral angles of 73.42 (8) and 71.28 (9)°, respectively, with the benzene ring. In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds generate R (2) (2)(8) loops and C—H⋯O interactions connect the dimers into corrugated sheets lying parallel to the bc plane. |
format | Online Article Text |
id | pubmed-3435804 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34358042012-09-11 (3′R)-3′-Benzyl-2′,3′-dihydro-1H-spiro[indole-3,1′-naphtho[2,3-c]pyrrole]-2,4′,9′-trione Sharma, Garima Kumar, S. Vasanth Wahab, Habibah A. Rosli, Mohd Mustaqim Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(26)H(18)N(2)O(3), the maximum deviations from planarity for the tetrahydro-1H-naphtho[2,3-c]pyrrole and indoline rings systems are 0.091 (1) and 0.012 (2) Å, respectively. These ring systems make a dihedral angle of 89.95 (6)° with each other and they make dihedral angles of 73.42 (8) and 71.28 (9)°, respectively, with the benzene ring. In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds generate R (2) (2)(8) loops and C—H⋯O interactions connect the dimers into corrugated sheets lying parallel to the bc plane. International Union of Crystallography 2012-08-25 /pmc/articles/PMC3435804/ /pubmed/22969650 http://dx.doi.org/10.1107/S1600536812036227 Text en © Sharma et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Sharma, Garima Kumar, S. Vasanth Wahab, Habibah A. Rosli, Mohd Mustaqim Fun, Hoong-Kun (3′R)-3′-Benzyl-2′,3′-dihydro-1H-spiro[indole-3,1′-naphtho[2,3-c]pyrrole]-2,4′,9′-trione |
title | (3′R)-3′-Benzyl-2′,3′-dihydro-1H-spiro[indole-3,1′-naphtho[2,3-c]pyrrole]-2,4′,9′-trione |
title_full | (3′R)-3′-Benzyl-2′,3′-dihydro-1H-spiro[indole-3,1′-naphtho[2,3-c]pyrrole]-2,4′,9′-trione |
title_fullStr | (3′R)-3′-Benzyl-2′,3′-dihydro-1H-spiro[indole-3,1′-naphtho[2,3-c]pyrrole]-2,4′,9′-trione |
title_full_unstemmed | (3′R)-3′-Benzyl-2′,3′-dihydro-1H-spiro[indole-3,1′-naphtho[2,3-c]pyrrole]-2,4′,9′-trione |
title_short | (3′R)-3′-Benzyl-2′,3′-dihydro-1H-spiro[indole-3,1′-naphtho[2,3-c]pyrrole]-2,4′,9′-trione |
title_sort | (3′r)-3′-benzyl-2′,3′-dihydro-1h-spiro[indole-3,1′-naphtho[2,3-c]pyrrole]-2,4′,9′-trione |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435804/ https://www.ncbi.nlm.nih.gov/pubmed/22969650 http://dx.doi.org/10.1107/S1600536812036227 |
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