Cargando…
1-Methyl-1′-(4-methylphenyl)-2′,3′,5′,6′,7′,7a’-hexahydro-1′H-dispiro[piperidine-3,2′-pyrrolizine-3′,3′′-indoline]-4,2′′-dione
The title compound, C(26)H(29)N(3)O(2), crystallizes with two molecules in the asymmetric unit, having C—H⋯O interactions between them and resulting in a dimer characterized by an R (2) (2)(11) motif. These dimers are linked into an ABABAB chain via N—H⋯O, N—H⋯N and C—H⋯O built edge-fused R (1) (2...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435806/ https://www.ncbi.nlm.nih.gov/pubmed/22969652 http://dx.doi.org/10.1107/S1600536812036240 |
Sumario: | The title compound, C(26)H(29)N(3)O(2), crystallizes with two molecules in the asymmetric unit, having C—H⋯O interactions between them and resulting in a dimer characterized by an R (2) (2)(11) motif. These dimers are linked into an ABABAB chain via N—H⋯O, N—H⋯N and C—H⋯O built edge-fused R (1) (2)(5) and R (2) (2)(7) motifs. This chain is linked to its inversion-related partner via N—H⋯O bonds with an R (2) (2)(8) motif and leads to a double chain extending along the b axis characterized by an R (6) (6)(36) motif across the inversion centres. The methyl group of the phenyl ring and the oxindole of molecule A and B are involved in C—H⋯π interactions. One C atom of the pyrrolizine ring of molecule A and its attached H atoms show positional disorder, the major and minor components being in the ratio 0.706 (7):0.294 (7). |
---|