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1-Methyl-1′-(4-methyl­phen­yl)-2′,3′,5′,6′,7′,7a’-hexa­hydro-1′H-dispiro­[piperidine-3,2′-pyrrolizine-3′,3′′-indoline]-4,2′′-dione

The title compound, C(26)H(29)N(3)O(2), crystallizes with two mol­ecules in the asymmetric unit, having C—H⋯O inter­actions between them and resulting in a dimer characterized by an R (2) (2)(11) motif. These dimers are linked into an ABABAB chain via N—H⋯O, N—H⋯N and C—H⋯O built edge-fused R (1) (2...

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Detalles Bibliográficos
Autores principales: Ramaswamy, S., Sribala, R., Srinivasan, N., Krishnakumar, R. V., Kumar, R. Ranjith
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435806/
https://www.ncbi.nlm.nih.gov/pubmed/22969652
http://dx.doi.org/10.1107/S1600536812036240
Descripción
Sumario:The title compound, C(26)H(29)N(3)O(2), crystallizes with two mol­ecules in the asymmetric unit, having C—H⋯O inter­actions between them and resulting in a dimer characterized by an R (2) (2)(11) motif. These dimers are linked into an ABABAB chain via N—H⋯O, N—H⋯N and C—H⋯O built edge-fused R (1) (2)(5) and R (2) (2)(7) motifs. This chain is linked to its inversion-related partner via N—H⋯O bonds with an R (2) (2)(8) motif and leads to a double chain extending along the b axis characterized by an R (6) (6)(36) motif across the inversion centres. The methyl group of the phenyl ring and the oxindole of mol­ecule A and B are involved in C—H⋯π inter­actions. One C atom of the pyrrolizine ring of mol­ecule A and its attached H atoms show positional disorder, the major and minor components being in the ratio 0.706 (7):0.294 (7).