(E)-N′-(3,4-Dimeth­oxy­benzyl­idene)-4-meth­oxy­benzohydrazide

In the title compound, C(17)H(18)N(2)O(4), the azomethine double bond adopts an E conformation with an N—N—C—C torsion angle of −178.3 (3)°. The benzene rings are almost coplaner, with a dihedral angle of 2.98 (14)° between their mean planes. In the crystal, the molecules are linked by N—H⋯O hydroge...

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Autores principales: Taha, Muhammad, Naz, Humera, Rahman, Aqilah Abd, Ismail, Nor Hadiani, Sammer, Yousuf
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435812/
https://www.ncbi.nlm.nih.gov/pubmed/22969658
http://dx.doi.org/10.1107/S1600536812034228
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author Taha, Muhammad
Naz, Humera
Rahman, Aqilah Abd
Ismail, Nor Hadiani
Sammer, Yousuf
author_facet Taha, Muhammad
Naz, Humera
Rahman, Aqilah Abd
Ismail, Nor Hadiani
Sammer, Yousuf
author_sort Taha, Muhammad
collection PubMed
description In the title compound, C(17)H(18)N(2)O(4), the azomethine double bond adopts an E conformation with an N—N—C—C torsion angle of −178.3 (3)°. The benzene rings are almost coplaner, with a dihedral angle of 2.98 (14)° between their mean planes. In the crystal, the molecules are linked by N—H⋯O hydrogen bonds, resulting in chains of mol­ecules lying parallel to the b axis. The structure is further consolidated by rather weak C—H⋯O hydrogen-bonding inter­actions, resulting in six-membered rings about inversion centers linked into chains arranged parallel to the b axis.
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spelling pubmed-34358122012-09-11 (E)-N′-(3,4-Dimeth­oxy­benzyl­idene)-4-meth­oxy­benzohydrazide Taha, Muhammad Naz, Humera Rahman, Aqilah Abd Ismail, Nor Hadiani Sammer, Yousuf Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(17)H(18)N(2)O(4), the azomethine double bond adopts an E conformation with an N—N—C—C torsion angle of −178.3 (3)°. The benzene rings are almost coplaner, with a dihedral angle of 2.98 (14)° between their mean planes. In the crystal, the molecules are linked by N—H⋯O hydrogen bonds, resulting in chains of mol­ecules lying parallel to the b axis. The structure is further consolidated by rather weak C—H⋯O hydrogen-bonding inter­actions, resulting in six-membered rings about inversion centers linked into chains arranged parallel to the b axis. International Union of Crystallography 2012-08-25 /pmc/articles/PMC3435812/ /pubmed/22969658 http://dx.doi.org/10.1107/S1600536812034228 Text en © Taha et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Taha, Muhammad
Naz, Humera
Rahman, Aqilah Abd
Ismail, Nor Hadiani
Sammer, Yousuf
(E)-N′-(3,4-Dimeth­oxy­benzyl­idene)-4-meth­oxy­benzohydrazide
title (E)-N′-(3,4-Dimeth­oxy­benzyl­idene)-4-meth­oxy­benzohydrazide
title_full (E)-N′-(3,4-Dimeth­oxy­benzyl­idene)-4-meth­oxy­benzohydrazide
title_fullStr (E)-N′-(3,4-Dimeth­oxy­benzyl­idene)-4-meth­oxy­benzohydrazide
title_full_unstemmed (E)-N′-(3,4-Dimeth­oxy­benzyl­idene)-4-meth­oxy­benzohydrazide
title_short (E)-N′-(3,4-Dimeth­oxy­benzyl­idene)-4-meth­oxy­benzohydrazide
title_sort (e)-n′-(3,4-dimeth­oxy­benzyl­idene)-4-meth­oxy­benzohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435812/
https://www.ncbi.nlm.nih.gov/pubmed/22969658
http://dx.doi.org/10.1107/S1600536812034228
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