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5-Amino-3-anilino-1H-pyrazole-4-carbonitrile

In the title compound, C(10)H(9)N(5), the phenyl ring is twisted with respect to the pyrazole ring, forming a dihedral angle of 24.00 (6)°. In the crystal, mol­ecules are linked by N—H⋯N hydrogen bonds into chains running parallel to [010] containing alternating R (2) (2)(6) and R (2) (2)(12) rings....

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Detalles Bibliográficos
Autores principales: Mohamed, Shaaban K., Akkurt, Mehmet, Fronczek, Frank R., El-Remaily, Mahmoud A. A., Abdelhamid, Antar A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435815/
https://www.ncbi.nlm.nih.gov/pubmed/22969661
http://dx.doi.org/10.1107/S1600536812036045
Descripción
Sumario:In the title compound, C(10)H(9)N(5), the phenyl ring is twisted with respect to the pyrazole ring, forming a dihedral angle of 24.00 (6)°. In the crystal, mol­ecules are linked by N—H⋯N hydrogen bonds into chains running parallel to [010] containing alternating R (2) (2)(6) and R (2) (2)(12) rings. Further inter­actions are found in the crystal, viz. N—H⋯π(phen­yl) inter­actions and weak face-to-face π–π stacking inter­actions [centroid–centroid distance = 3.8890 (6) Å] between the centroids of the pyrazole and phenyl rings are observed.