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N′-[(E)-4-Benzyloxy-2-hydroxybenzylidene]benzohydrazide
The title compound, C(21)H(18)N(2)O(3), exists in the E conformation with respect to the azomethane C=N double bond. The central benzene ring is almost coplanar with one of the substituent benzene rings [dihedral angle = 1.74 (5)°] and is approximately orthogonal to the other benzene ring of the mol...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435816/ https://www.ncbi.nlm.nih.gov/pubmed/22969662 http://dx.doi.org/10.1107/S1600536812036306 |
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author | Reshma, P. R. Sithambaresan, M. Kurup, M. R. Prathapachandra |
author_facet | Reshma, P. R. Sithambaresan, M. Kurup, M. R. Prathapachandra |
author_sort | Reshma, P. R. |
collection | PubMed |
description | The title compound, C(21)H(18)N(2)O(3), exists in the E conformation with respect to the azomethane C=N double bond. The central benzene ring is almost coplanar with one of the substituent benzene rings [dihedral angle = 1.74 (5)°] and is approximately orthogonal to the other benzene ring of the molecule [dihedral angle = 86.61 (7)°]. An intramolecular O—H⋯N hydrogen bond occurs. The crystal packing is dominated by N—H⋯O hydrogen bonds, which lead to an infinite chain running parallel to [010]. |
format | Online Article Text |
id | pubmed-3435816 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34358162012-09-11 N′-[(E)-4-Benzyloxy-2-hydroxybenzylidene]benzohydrazide Reshma, P. R. Sithambaresan, M. Kurup, M. R. Prathapachandra Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(21)H(18)N(2)O(3), exists in the E conformation with respect to the azomethane C=N double bond. The central benzene ring is almost coplanar with one of the substituent benzene rings [dihedral angle = 1.74 (5)°] and is approximately orthogonal to the other benzene ring of the molecule [dihedral angle = 86.61 (7)°]. An intramolecular O—H⋯N hydrogen bond occurs. The crystal packing is dominated by N—H⋯O hydrogen bonds, which lead to an infinite chain running parallel to [010]. International Union of Crystallography 2012-08-25 /pmc/articles/PMC3435816/ /pubmed/22969662 http://dx.doi.org/10.1107/S1600536812036306 Text en © Reshma et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Reshma, P. R. Sithambaresan, M. Kurup, M. R. Prathapachandra N′-[(E)-4-Benzyloxy-2-hydroxybenzylidene]benzohydrazide |
title |
N′-[(E)-4-Benzyloxy-2-hydroxybenzylidene]benzohydrazide |
title_full |
N′-[(E)-4-Benzyloxy-2-hydroxybenzylidene]benzohydrazide |
title_fullStr |
N′-[(E)-4-Benzyloxy-2-hydroxybenzylidene]benzohydrazide |
title_full_unstemmed |
N′-[(E)-4-Benzyloxy-2-hydroxybenzylidene]benzohydrazide |
title_short |
N′-[(E)-4-Benzyloxy-2-hydroxybenzylidene]benzohydrazide |
title_sort | n′-[(e)-4-benzyloxy-2-hydroxybenzylidene]benzohydrazide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435816/ https://www.ncbi.nlm.nih.gov/pubmed/22969662 http://dx.doi.org/10.1107/S1600536812036306 |
work_keys_str_mv | AT reshmapr ne4benzyloxy2hydroxybenzylidenebenzohydrazide AT sithambaresanm ne4benzyloxy2hydroxybenzylidenebenzohydrazide AT kurupmrprathapachandra ne4benzyloxy2hydroxybenzylidenebenzohydrazide |