4-Meth­oxy-2-{(E)-[(thio­phen-2-yl)methyl­imino]­meth­yl}phenol

The title Schiff base, C(13)H(13)NO(2)S, adopts the phenol–imine tautomeric form and reveals an intra­molecular O—H⋯N hydrogen bond involving the hy­droxy group and the imino N atom, forming an S(6) ring. The mol­ecule is highly twisted with respect to the central imine group, which is reflected in...

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Autores principales: Kantar, Esen Nur, Köysal, Yavuz, Macit, Mustafa, Er, Ebru, Soylu, Mustafa Serkan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435828/
https://www.ncbi.nlm.nih.gov/pubmed/22969674
http://dx.doi.org/10.1107/S1600536812036586
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author Kantar, Esen Nur
Köysal, Yavuz
Macit, Mustafa
Er, Ebru
Soylu, Mustafa Serkan
author_facet Kantar, Esen Nur
Köysal, Yavuz
Macit, Mustafa
Er, Ebru
Soylu, Mustafa Serkan
author_sort Kantar, Esen Nur
collection PubMed
description The title Schiff base, C(13)H(13)NO(2)S, adopts the phenol–imine tautomeric form and reveals an intra­molecular O—H⋯N hydrogen bond involving the hy­droxy group and the imino N atom, forming an S(6) ring. The mol­ecule is highly twisted with respect to the central imine group, which is reflected in the dihedral angle of 67.83 (10)° formed by the thienyl and phenol rings. The crystal packing is characterized by weak C—H⋯O and C—H⋯π inter­actions.
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spelling pubmed-34358282012-09-11 4-Meth­oxy-2-{(E)-[(thio­phen-2-yl)methyl­imino]­meth­yl}phenol Kantar, Esen Nur Köysal, Yavuz Macit, Mustafa Er, Ebru Soylu, Mustafa Serkan Acta Crystallogr Sect E Struct Rep Online Organic Papers The title Schiff base, C(13)H(13)NO(2)S, adopts the phenol–imine tautomeric form and reveals an intra­molecular O—H⋯N hydrogen bond involving the hy­droxy group and the imino N atom, forming an S(6) ring. The mol­ecule is highly twisted with respect to the central imine group, which is reflected in the dihedral angle of 67.83 (10)° formed by the thienyl and phenol rings. The crystal packing is characterized by weak C—H⋯O and C—H⋯π inter­actions. International Union of Crystallography 2012-08-31 /pmc/articles/PMC3435828/ /pubmed/22969674 http://dx.doi.org/10.1107/S1600536812036586 Text en © Kantar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kantar, Esen Nur
Köysal, Yavuz
Macit, Mustafa
Er, Ebru
Soylu, Mustafa Serkan
4-Meth­oxy-2-{(E)-[(thio­phen-2-yl)methyl­imino]­meth­yl}phenol
title 4-Meth­oxy-2-{(E)-[(thio­phen-2-yl)methyl­imino]­meth­yl}phenol
title_full 4-Meth­oxy-2-{(E)-[(thio­phen-2-yl)methyl­imino]­meth­yl}phenol
title_fullStr 4-Meth­oxy-2-{(E)-[(thio­phen-2-yl)methyl­imino]­meth­yl}phenol
title_full_unstemmed 4-Meth­oxy-2-{(E)-[(thio­phen-2-yl)methyl­imino]­meth­yl}phenol
title_short 4-Meth­oxy-2-{(E)-[(thio­phen-2-yl)methyl­imino]­meth­yl}phenol
title_sort 4-meth­oxy-2-{(e)-[(thio­phen-2-yl)methyl­imino]­meth­yl}phenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435828/
https://www.ncbi.nlm.nih.gov/pubmed/22969674
http://dx.doi.org/10.1107/S1600536812036586
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