N-(2-Bromo­benz­yl)cinchoninium bromide

The title compound {systematic name: 1-(2-bromo­benz­yl)-5-ethenyl-2-[hy­droxy(quinolin-4-yl)meth­yl]-1-aza­bicyclo­[2.2.2]octan-1-ium bromide}, C(26)H(28)BrN(2)O(+)·Br(−), is a chiral quater­nary ammonium salt of one of the Cinchona alkaloids. The planes of the quinoline and of the bromo­benzyl sub...

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Autores principales: Skórska-Stania, Agnieszka, Jezierska-Zięba, Magdalena, Kąkol, Barbara, Fedoryński, Michał, Oleksyn, Barbara J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435830/
https://www.ncbi.nlm.nih.gov/pubmed/22969676
http://dx.doi.org/10.1107/S160053681203646X
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author Skórska-Stania, Agnieszka
Jezierska-Zięba, Magdalena
Kąkol, Barbara
Fedoryński, Michał
Oleksyn, Barbara J.
author_facet Skórska-Stania, Agnieszka
Jezierska-Zięba, Magdalena
Kąkol, Barbara
Fedoryński, Michał
Oleksyn, Barbara J.
author_sort Skórska-Stania, Agnieszka
collection PubMed
description The title compound {systematic name: 1-(2-bromo­benz­yl)-5-ethenyl-2-[hy­droxy(quinolin-4-yl)meth­yl]-1-aza­bicyclo­[2.2.2]octan-1-ium bromide}, C(26)H(28)BrN(2)O(+)·Br(−), is a chiral quater­nary ammonium salt of one of the Cinchona alkaloids. The planes of the quinoline and of the bromo­benzyl substituent are inclined to one another by 9.11 (9)°. A weak intra­molecular C—H⋯O hydrogen bond occurs. The crystal structure features strong O—H⋯Br hydrogen bonds and weak C—H⋯Br inter­actions.
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spelling pubmed-34358302012-09-11 N-(2-Bromo­benz­yl)cinchoninium bromide Skórska-Stania, Agnieszka Jezierska-Zięba, Magdalena Kąkol, Barbara Fedoryński, Michał Oleksyn, Barbara J. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound {systematic name: 1-(2-bromo­benz­yl)-5-ethenyl-2-[hy­droxy(quinolin-4-yl)meth­yl]-1-aza­bicyclo­[2.2.2]octan-1-ium bromide}, C(26)H(28)BrN(2)O(+)·Br(−), is a chiral quater­nary ammonium salt of one of the Cinchona alkaloids. The planes of the quinoline and of the bromo­benzyl substituent are inclined to one another by 9.11 (9)°. A weak intra­molecular C—H⋯O hydrogen bond occurs. The crystal structure features strong O—H⋯Br hydrogen bonds and weak C—H⋯Br inter­actions. International Union of Crystallography 2012-08-31 /pmc/articles/PMC3435830/ /pubmed/22969676 http://dx.doi.org/10.1107/S160053681203646X Text en © Skórska-Stania et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Skórska-Stania, Agnieszka
Jezierska-Zięba, Magdalena
Kąkol, Barbara
Fedoryński, Michał
Oleksyn, Barbara J.
N-(2-Bromo­benz­yl)cinchoninium bromide
title N-(2-Bromo­benz­yl)cinchoninium bromide
title_full N-(2-Bromo­benz­yl)cinchoninium bromide
title_fullStr N-(2-Bromo­benz­yl)cinchoninium bromide
title_full_unstemmed N-(2-Bromo­benz­yl)cinchoninium bromide
title_short N-(2-Bromo­benz­yl)cinchoninium bromide
title_sort n-(2-bromo­benz­yl)cinchoninium bromide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435830/
https://www.ncbi.nlm.nih.gov/pubmed/22969676
http://dx.doi.org/10.1107/S160053681203646X
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AT jezierskaziebamagdalena n2bromobenzylcinchoniniumbromide
AT kakolbarbara n2bromobenzylcinchoniniumbromide
AT fedorynskimichał n2bromobenzylcinchoniniumbromide
AT oleksynbarbaraj n2bromobenzylcinchoniniumbromide

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