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Redetermination of 4-cyano­pyridine N-oxide

In the title pyridine N-oxide derivative, C(6)H(4)N(2)O, the 4-cyano substituent almost lies in the mean plane of the pyridine ring (r.m.s deviation of all non-H atoms = 0.004 Å). This redetermination results in a crystal structure with significantly higher precision [N—O bond length is 1.2997 (15)...

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Detalles Bibliográficos
Autores principales: Moreno-Fuquen, Rodolfo, Arana, Carolina, De Simone, Carlos A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435831/
https://www.ncbi.nlm.nih.gov/pubmed/22969677
http://dx.doi.org/10.1107/S1600536812036690
Descripción
Sumario:In the title pyridine N-oxide derivative, C(6)H(4)N(2)O, the 4-cyano substituent almost lies in the mean plane of the pyridine ring (r.m.s deviation of all non-H atoms = 0.004 Å). This redetermination results in a crystal structure with significantly higher precision [N—O bond length is 1.2997 (15) compared with 1.303 (5) Å in the original] than the original determination, which was recorded using the multiple-film technique and visually estimated intensities [Hardcastle et al. (1974 ▶). J. Cryst. Mol. Struct. 4, 305–311]. The crystal structure features weak C—H⋯O and C—H⋯N inter­actions, which lead to the formation of chains that inter­sect each other parallel to (001).