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6-(4-Aminophenyl)-4-(4-ethoxyphenyl)-2-methoxynicotinonitrile
In the title molecule, C(21)H(19)N(3)O(2), the central pyridine ring makes dihedral angles of 14.46 (9) and 34.67 (8)° with the 4-amino- and 4-ethoxy-substituted benzene rings, respectively. The ethoxy group is essentially coplanar with the attached benzene ring [C—O—C—C torsion angle = 178.70 (1...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435837/ https://www.ncbi.nlm.nih.gov/pubmed/22969683 http://dx.doi.org/10.1107/S1600536812036276 |
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author | Suwunwong, Thitipone Chantrapromma, Suchada Fun, Hoong-Kun |
author_facet | Suwunwong, Thitipone Chantrapromma, Suchada Fun, Hoong-Kun |
author_sort | Suwunwong, Thitipone |
collection | PubMed |
description | In the title molecule, C(21)H(19)N(3)O(2), the central pyridine ring makes dihedral angles of 14.46 (9) and 34.67 (8)° with the 4-amino- and 4-ethoxy-substituted benzene rings, respectively. The ethoxy group is essentially coplanar with the attached benzene ring [C—O—C—C torsion angle = 178.70 (16)°] as is the methoxy group with the pyridine ring [C—O—C—N torsion angle = −3.0 (3)°]. In the crystal, molecules are linked by N—H⋯N hydrogen bonds into chains along [201]. Weak C—H⋯O hydrogen bonds and C—H⋯π interactions are also present. |
format | Online Article Text |
id | pubmed-3435837 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34358372012-09-11 6-(4-Aminophenyl)-4-(4-ethoxyphenyl)-2-methoxynicotinonitrile Suwunwong, Thitipone Chantrapromma, Suchada Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title molecule, C(21)H(19)N(3)O(2), the central pyridine ring makes dihedral angles of 14.46 (9) and 34.67 (8)° with the 4-amino- and 4-ethoxy-substituted benzene rings, respectively. The ethoxy group is essentially coplanar with the attached benzene ring [C—O—C—C torsion angle = 178.70 (16)°] as is the methoxy group with the pyridine ring [C—O—C—N torsion angle = −3.0 (3)°]. In the crystal, molecules are linked by N—H⋯N hydrogen bonds into chains along [201]. Weak C—H⋯O hydrogen bonds and C—H⋯π interactions are also present. International Union of Crystallography 2012-08-31 /pmc/articles/PMC3435837/ /pubmed/22969683 http://dx.doi.org/10.1107/S1600536812036276 Text en © Suwunwong et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Suwunwong, Thitipone Chantrapromma, Suchada Fun, Hoong-Kun 6-(4-Aminophenyl)-4-(4-ethoxyphenyl)-2-methoxynicotinonitrile |
title | 6-(4-Aminophenyl)-4-(4-ethoxyphenyl)-2-methoxynicotinonitrile |
title_full | 6-(4-Aminophenyl)-4-(4-ethoxyphenyl)-2-methoxynicotinonitrile |
title_fullStr | 6-(4-Aminophenyl)-4-(4-ethoxyphenyl)-2-methoxynicotinonitrile |
title_full_unstemmed | 6-(4-Aminophenyl)-4-(4-ethoxyphenyl)-2-methoxynicotinonitrile |
title_short | 6-(4-Aminophenyl)-4-(4-ethoxyphenyl)-2-methoxynicotinonitrile |
title_sort | 6-(4-aminophenyl)-4-(4-ethoxyphenyl)-2-methoxynicotinonitrile |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435837/ https://www.ncbi.nlm.nih.gov/pubmed/22969683 http://dx.doi.org/10.1107/S1600536812036276 |
work_keys_str_mv | AT suwunwongthitipone 64aminophenyl44ethoxyphenyl2methoxynicotinonitrile AT chantraprommasuchada 64aminophenyl44ethoxyphenyl2methoxynicotinonitrile AT funhoongkun 64aminophenyl44ethoxyphenyl2methoxynicotinonitrile |