(E)-4-(2-Hy­droxy-3-meth­oxy­benzyl­idene­amino)-6-methyl-3-sulfanyl­idene-3,4-dihydro-1,2,4-triazin-5(2H)-one

In the title mol­ecule, C(12)H(12)N(4)O(3)S, there is an intra­molecular O—H⋯N hydrogen bond. The dihedral angle between the benzene and triazine rings is 65.9 (3)°. In the crystal, N—H⋯S and O—H⋯N hydrogen bonds link the mol­ecules into chains along [010]. In addition, there are weak π–π stacking i...

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Autores principales: Shirinkam, Bahareh, Tabatabaee, Masoumeh, Gassemzadeh, Mitra, Neumuller, Bernhard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435839/
https://www.ncbi.nlm.nih.gov/pubmed/22969685
http://dx.doi.org/10.1107/S1600536812036756
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author Shirinkam, Bahareh
Tabatabaee, Masoumeh
Gassemzadeh, Mitra
Neumuller, Bernhard
author_facet Shirinkam, Bahareh
Tabatabaee, Masoumeh
Gassemzadeh, Mitra
Neumuller, Bernhard
author_sort Shirinkam, Bahareh
collection PubMed
description In the title mol­ecule, C(12)H(12)N(4)O(3)S, there is an intra­molecular O—H⋯N hydrogen bond. The dihedral angle between the benzene and triazine rings is 65.9 (3)°. In the crystal, N—H⋯S and O—H⋯N hydrogen bonds link the mol­ecules into chains along [010]. In addition, there are weak π–π stacking inter­actions between symmetry-related triazine rings with a centroid–centroid distance of 3.560 (3)°.
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spelling pubmed-34358392012-09-11 (E)-4-(2-Hy­droxy-3-meth­oxy­benzyl­idene­amino)-6-methyl-3-sulfanyl­idene-3,4-dihydro-1,2,4-triazin-5(2H)-one Shirinkam, Bahareh Tabatabaee, Masoumeh Gassemzadeh, Mitra Neumuller, Bernhard Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(12)H(12)N(4)O(3)S, there is an intra­molecular O—H⋯N hydrogen bond. The dihedral angle between the benzene and triazine rings is 65.9 (3)°. In the crystal, N—H⋯S and O—H⋯N hydrogen bonds link the mol­ecules into chains along [010]. In addition, there are weak π–π stacking inter­actions between symmetry-related triazine rings with a centroid–centroid distance of 3.560 (3)°. International Union of Crystallography 2012-08-31 /pmc/articles/PMC3435839/ /pubmed/22969685 http://dx.doi.org/10.1107/S1600536812036756 Text en © Shirinkam et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Shirinkam, Bahareh
Tabatabaee, Masoumeh
Gassemzadeh, Mitra
Neumuller, Bernhard
(E)-4-(2-Hy­droxy-3-meth­oxy­benzyl­idene­amino)-6-methyl-3-sulfanyl­idene-3,4-dihydro-1,2,4-triazin-5(2H)-one
title (E)-4-(2-Hy­droxy-3-meth­oxy­benzyl­idene­amino)-6-methyl-3-sulfanyl­idene-3,4-dihydro-1,2,4-triazin-5(2H)-one
title_full (E)-4-(2-Hy­droxy-3-meth­oxy­benzyl­idene­amino)-6-methyl-3-sulfanyl­idene-3,4-dihydro-1,2,4-triazin-5(2H)-one
title_fullStr (E)-4-(2-Hy­droxy-3-meth­oxy­benzyl­idene­amino)-6-methyl-3-sulfanyl­idene-3,4-dihydro-1,2,4-triazin-5(2H)-one
title_full_unstemmed (E)-4-(2-Hy­droxy-3-meth­oxy­benzyl­idene­amino)-6-methyl-3-sulfanyl­idene-3,4-dihydro-1,2,4-triazin-5(2H)-one
title_short (E)-4-(2-Hy­droxy-3-meth­oxy­benzyl­idene­amino)-6-methyl-3-sulfanyl­idene-3,4-dihydro-1,2,4-triazin-5(2H)-one
title_sort (e)-4-(2-hy­droxy-3-meth­oxy­benzyl­idene­amino)-6-methyl-3-sulfanyl­idene-3,4-dihydro-1,2,4-triazin-5(2h)-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435839/
https://www.ncbi.nlm.nih.gov/pubmed/22969685
http://dx.doi.org/10.1107/S1600536812036756
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