Formation of Nb(2)O(5) matrix and Vis-NIR absorption in Nb-Ge-O thin film

This paper investigates the crystal structure and optical absorption of Ge-doped Nb-oxide (Nb-Ge-O) thin films prepared by RF sputtering. A wide-gap material, Nb(2)O(5), is selectively produced as a matrix to disperse Ge nanocrystals through compositional optimization with Ge chip numbers and oxygen ratio in argon. The optical-absorption spectra are obviously shifted to visible (vis) and near-infrared (NIR) regions, suggesting that a composite thin film with Ge nanocrystals dispersed in Nb(2)O(5) matrix exhibits quantum-size effects. Accordingly, the two valuable characteristics of the Nb(2)O(5) matrix and the vis-NIR absorption are found to be retained simultaneously in Nb-Ge-O thin films.