Mechanistic Investigation of Methylphosphonate Synthase, a Non-Heme Iron-Dependent Oxygenase

[Image: see text] Methylphosphonate synthase is a non-heme iron-dependent oxygenase that converts 2-hydroxyethylphosphonate (2-HEP) to methylphosphonate. On the basis of experiments with two enantiomers of a substrate analog, 2-hydroxypropylphosphonate, catalysis is proposed to commence with stereos...

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Detalles Bibliográficos
Autores principales: Cooke, Heather A., Peck, Spencer C., Evans, Bradley S., van der Donk, Wilfred A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2012
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3458437/
https://www.ncbi.nlm.nih.gov/pubmed/22957470
http://dx.doi.org/10.1021/ja306777w

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3458437/
https://www.ncbi.nlm.nih.gov/pubmed/22957470
http://dx.doi.org/10.1021/ja306777w

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