Photoreactions of cyclic sulfite esters: Evidence for diradical intermediates

The photochemistry of a phenyl and 1,2-diphenyl substituted sulfite ester is reported. The performance of photoreactions under relatively mild reaction conditions enables the detection of products that have not been observed in previous studies. It is concluded that, complementary to the initially p...

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Detalles Bibliográficos
Autores principales: White, Rick C, Arney, Benny E, Ihmels, Heiko
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2012
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3458739/
https://www.ncbi.nlm.nih.gov/pubmed/23019449
http://dx.doi.org/10.3762/bjoc.8.134
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author White, Rick C
Arney, Benny E
Ihmels, Heiko
author_facet White, Rick C
Arney, Benny E
Ihmels, Heiko
author_sort White, Rick C
collection PubMed
description The photochemistry of a phenyl and 1,2-diphenyl substituted sulfite ester is reported. The performance of photoreactions under relatively mild reaction conditions enables the detection of products that have not been observed in previous studies. It is concluded that, complementary to the initially proposed carbene intermediates, diradicals may also be considered.
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spelling pubmed-34587392012-09-27 Photoreactions of cyclic sulfite esters: Evidence for diradical intermediates White, Rick C Arney, Benny E Ihmels, Heiko Beilstein J Org Chem Full Research Paper The photochemistry of a phenyl and 1,2-diphenyl substituted sulfite ester is reported. The performance of photoreactions under relatively mild reaction conditions enables the detection of products that have not been observed in previous studies. It is concluded that, complementary to the initially proposed carbene intermediates, diradicals may also be considered. Beilstein-Institut 2012-07-30 /pmc/articles/PMC3458739/ /pubmed/23019449 http://dx.doi.org/10.3762/bjoc.8.134 Text en Copyright © 2012, White et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
White, Rick C
Arney, Benny E
Ihmels, Heiko
Photoreactions of cyclic sulfite esters: Evidence for diradical intermediates
title Photoreactions of cyclic sulfite esters: Evidence for diradical intermediates
title_full Photoreactions of cyclic sulfite esters: Evidence for diradical intermediates
title_fullStr Photoreactions of cyclic sulfite esters: Evidence for diradical intermediates
title_full_unstemmed Photoreactions of cyclic sulfite esters: Evidence for diradical intermediates
title_short Photoreactions of cyclic sulfite esters: Evidence for diradical intermediates
title_sort photoreactions of cyclic sulfite esters: evidence for diradical intermediates
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3458739/
https://www.ncbi.nlm.nih.gov/pubmed/23019449
http://dx.doi.org/10.3762/bjoc.8.134
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