(η(6)-Benzene)­(benzyl­diphenyl­phos­phane)dichloridoruthenium(II)

In the title compound, [RuCl(2)(C(6)H(6))(C(19)H(17)P)], the Ru(II) atom has a distorted pseudo-octa­hedral coordination environment with the metrical parameters around the metallic core as Ru—centroid(η(6)-benzene) = 1.6894 (11) Å, Ru—P = 2.3466 (6), Ru—Cl(avg.) = 2.4127 (7) Å; Cl—Ru—Cl = 88.07 (2)...

Descripción completa

Detalles Bibliográficos
Autores principales: Muller, Alfred, Davis, Wade L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470126/
https://www.ncbi.nlm.nih.gov/pubmed/23125570
http://dx.doi.org/10.1107/S1600536812037154
_version_ 1782246200894816256
author Muller, Alfred
Davis, Wade L.
author_facet Muller, Alfred
Davis, Wade L.
author_sort Muller, Alfred
collection PubMed
description In the title compound, [RuCl(2)(C(6)H(6))(C(19)H(17)P)], the Ru(II) atom has a distorted pseudo-octa­hedral coordination environment with the metrical parameters around the metallic core as Ru—centroid(η(6)-benzene) = 1.6894 (11) Å, Ru—P = 2.3466 (6), Ru—Cl(avg.) = 2.4127 (7) Å; Cl—Ru—Cl = 88.07 (2) and Cl—Ru—P = 82.77 (2), 87.65 (2)°. The effective cone angle for the benzyl­diphenyl­phosphane was calculated to be 143°. In the crystal C—H⋯Cl and C—H⋯π inter­actions are observed.
format Online
Article
Text
id pubmed-3470126
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-34701262012-11-02 (η(6)-Benzene)­(benzyl­diphenyl­phos­phane)dichloridoruthenium(II) Muller, Alfred Davis, Wade L. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [RuCl(2)(C(6)H(6))(C(19)H(17)P)], the Ru(II) atom has a distorted pseudo-octa­hedral coordination environment with the metrical parameters around the metallic core as Ru—centroid(η(6)-benzene) = 1.6894 (11) Å, Ru—P = 2.3466 (6), Ru—Cl(avg.) = 2.4127 (7) Å; Cl—Ru—Cl = 88.07 (2) and Cl—Ru—P = 82.77 (2), 87.65 (2)°. The effective cone angle for the benzyl­diphenyl­phosphane was calculated to be 143°. In the crystal C—H⋯Cl and C—H⋯π inter­actions are observed. International Union of Crystallography 2012-09-01 /pmc/articles/PMC3470126/ /pubmed/23125570 http://dx.doi.org/10.1107/S1600536812037154 Text en © Muller and Davis 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Muller, Alfred
Davis, Wade L.
(η(6)-Benzene)­(benzyl­diphenyl­phos­phane)dichloridoruthenium(II)
title (η(6)-Benzene)­(benzyl­diphenyl­phos­phane)dichloridoruthenium(II)
title_full (η(6)-Benzene)­(benzyl­diphenyl­phos­phane)dichloridoruthenium(II)
title_fullStr (η(6)-Benzene)­(benzyl­diphenyl­phos­phane)dichloridoruthenium(II)
title_full_unstemmed (η(6)-Benzene)­(benzyl­diphenyl­phos­phane)dichloridoruthenium(II)
title_short (η(6)-Benzene)­(benzyl­diphenyl­phos­phane)dichloridoruthenium(II)
title_sort (η(6)-benzene)­(benzyl­diphenyl­phos­phane)dichloridoruthenium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470126/
https://www.ncbi.nlm.nih.gov/pubmed/23125570
http://dx.doi.org/10.1107/S1600536812037154
work_keys_str_mv AT mulleralfred ē6benzenebenzyldiphenylphosphanedichloridorutheniumii
AT daviswadel ē6benzenebenzyldiphenylphosphanedichloridorutheniumii

Ejemplares similares