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Tetrakis(dimethylammonium) trans-dichloridobis[5,5′-(pyrazine-2,3-diyl)bis(1H-tetrazol-1-ido-κN (1))]copper(II)
The title compound, (C(2)H(8)N)(4)[Cu(C(6)H(2)N(10))(2)Cl(2)], consists of an anionic complex which is composed of a Cu(II) ion surrounded by four N atoms from two pyrazine-2,3-diylbis(1H-tetrazol-1-ide) ligands, and two Cl(−) atoms in a trans-Cl(2)N(4) coordination geometry; the Cu(II) atom lies o...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470127/ https://www.ncbi.nlm.nih.gov/pubmed/23125571 http://dx.doi.org/10.1107/S1600536812036896 |
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author | Liao, Ju-Hsiou Shi, Pei-Shan |
author_facet | Liao, Ju-Hsiou Shi, Pei-Shan |
author_sort | Liao, Ju-Hsiou |
collection | PubMed |
description | The title compound, (C(2)H(8)N)(4)[Cu(C(6)H(2)N(10))(2)Cl(2)], consists of an anionic complex which is composed of a Cu(II) ion surrounded by four N atoms from two pyrazine-2,3-diylbis(1H-tetrazol-1-ide) ligands, and two Cl(−) atoms in a trans-Cl(2)N(4) coordination geometry; the Cu(II) atom lies on a site of symmetry 2/m. The Cu—Cl distance of 2.8719 (5) Å is long due to the Jahn–Teller distortion of the d (9) electron configuration of Cu(II) ion. The tetrazole and pyrazine rings make an N—C—C—N torsion angle of 38.25 (17)°. The charge of the anionic complex is balanced by four dimethylammonium cations, which interact with the anionic complexes via N—H⋯N and N—H⋯Cl hydrogen bonds. |
format | Online Article Text |
id | pubmed-3470127 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34701272012-11-02 Tetrakis(dimethylammonium) trans-dichloridobis[5,5′-(pyrazine-2,3-diyl)bis(1H-tetrazol-1-ido-κN (1))]copper(II) Liao, Ju-Hsiou Shi, Pei-Shan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(2)H(8)N)(4)[Cu(C(6)H(2)N(10))(2)Cl(2)], consists of an anionic complex which is composed of a Cu(II) ion surrounded by four N atoms from two pyrazine-2,3-diylbis(1H-tetrazol-1-ide) ligands, and two Cl(−) atoms in a trans-Cl(2)N(4) coordination geometry; the Cu(II) atom lies on a site of symmetry 2/m. The Cu—Cl distance of 2.8719 (5) Å is long due to the Jahn–Teller distortion of the d (9) electron configuration of Cu(II) ion. The tetrazole and pyrazine rings make an N—C—C—N torsion angle of 38.25 (17)°. The charge of the anionic complex is balanced by four dimethylammonium cations, which interact with the anionic complexes via N—H⋯N and N—H⋯Cl hydrogen bonds. International Union of Crystallography 2012-09-01 /pmc/articles/PMC3470127/ /pubmed/23125571 http://dx.doi.org/10.1107/S1600536812036896 Text en © Liao and Shi 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Liao, Ju-Hsiou Shi, Pei-Shan Tetrakis(dimethylammonium) trans-dichloridobis[5,5′-(pyrazine-2,3-diyl)bis(1H-tetrazol-1-ido-κN (1))]copper(II) |
title | Tetrakis(dimethylammonium) trans-dichloridobis[5,5′-(pyrazine-2,3-diyl)bis(1H-tetrazol-1-ido-κN
(1))]copper(II) |
title_full | Tetrakis(dimethylammonium) trans-dichloridobis[5,5′-(pyrazine-2,3-diyl)bis(1H-tetrazol-1-ido-κN
(1))]copper(II) |
title_fullStr | Tetrakis(dimethylammonium) trans-dichloridobis[5,5′-(pyrazine-2,3-diyl)bis(1H-tetrazol-1-ido-κN
(1))]copper(II) |
title_full_unstemmed | Tetrakis(dimethylammonium) trans-dichloridobis[5,5′-(pyrazine-2,3-diyl)bis(1H-tetrazol-1-ido-κN
(1))]copper(II) |
title_short | Tetrakis(dimethylammonium) trans-dichloridobis[5,5′-(pyrazine-2,3-diyl)bis(1H-tetrazol-1-ido-κN
(1))]copper(II) |
title_sort | tetrakis(dimethylammonium) trans-dichloridobis[5,5′-(pyrazine-2,3-diyl)bis(1h-tetrazol-1-ido-κn
(1))]copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470127/ https://www.ncbi.nlm.nih.gov/pubmed/23125571 http://dx.doi.org/10.1107/S1600536812036896 |
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