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Tetra­kis(dimethyl­ammonium) trans-di­chloridobis[5,5′-(pyrazine-2,3-diyl)bis(1H-tetra­zol-1-ido-κN (1))]copper(II)

The title compound, (C(2)H(8)N)(4)[Cu(C(6)H(2)N(10))(2)Cl(2)], consists of an anionic complex which is composed of a Cu(II) ion surrounded by four N atoms from two pyrazine-2,3-diylbis(1H-tetra­zol-1-ide) ligands, and two Cl(−) atoms in a trans-Cl(2)N(4) coordination geometry; the Cu(II) atom lies o...

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Autores principales: Liao, Ju-Hsiou, Shi, Pei-Shan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470127/
https://www.ncbi.nlm.nih.gov/pubmed/23125571
http://dx.doi.org/10.1107/S1600536812036896
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author Liao, Ju-Hsiou
Shi, Pei-Shan
author_facet Liao, Ju-Hsiou
Shi, Pei-Shan
author_sort Liao, Ju-Hsiou
collection PubMed
description The title compound, (C(2)H(8)N)(4)[Cu(C(6)H(2)N(10))(2)Cl(2)], consists of an anionic complex which is composed of a Cu(II) ion surrounded by four N atoms from two pyrazine-2,3-diylbis(1H-tetra­zol-1-ide) ligands, and two Cl(−) atoms in a trans-Cl(2)N(4) coordination geometry; the Cu(II) atom lies on a site of symmetry 2/m. The Cu—Cl distance of 2.8719 (5) Å is long due to the Jahn–Teller distortion of the d (9) electron configuration of Cu(II) ion. The tetra­zole and pyrazine rings make an N—C—C—N torsion angle of 38.25 (17)°. The charge of the anionic complex is balanced by four dimethyl­ammonium cations, which inter­act with the anionic complexes via N—H⋯N and N—H⋯Cl hydrogen bonds.
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spelling pubmed-34701272012-11-02 Tetra­kis(dimethyl­ammonium) trans-di­chloridobis[5,5′-(pyrazine-2,3-diyl)bis(1H-tetra­zol-1-ido-κN (1))]copper(II) Liao, Ju-Hsiou Shi, Pei-Shan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(2)H(8)N)(4)[Cu(C(6)H(2)N(10))(2)Cl(2)], consists of an anionic complex which is composed of a Cu(II) ion surrounded by four N atoms from two pyrazine-2,3-diylbis(1H-tetra­zol-1-ide) ligands, and two Cl(−) atoms in a trans-Cl(2)N(4) coordination geometry; the Cu(II) atom lies on a site of symmetry 2/m. The Cu—Cl distance of 2.8719 (5) Å is long due to the Jahn–Teller distortion of the d (9) electron configuration of Cu(II) ion. The tetra­zole and pyrazine rings make an N—C—C—N torsion angle of 38.25 (17)°. The charge of the anionic complex is balanced by four dimethyl­ammonium cations, which inter­act with the anionic complexes via N—H⋯N and N—H⋯Cl hydrogen bonds. International Union of Crystallography 2012-09-01 /pmc/articles/PMC3470127/ /pubmed/23125571 http://dx.doi.org/10.1107/S1600536812036896 Text en © Liao and Shi 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liao, Ju-Hsiou
Shi, Pei-Shan
Tetra­kis(dimethyl­ammonium) trans-di­chloridobis[5,5′-(pyrazine-2,3-diyl)bis(1H-tetra­zol-1-ido-κN (1))]copper(II)
title Tetra­kis(dimethyl­ammonium) trans-di­chloridobis[5,5′-(pyrazine-2,3-diyl)bis(1H-tetra­zol-1-ido-κN (1))]copper(II)
title_full Tetra­kis(dimethyl­ammonium) trans-di­chloridobis[5,5′-(pyrazine-2,3-diyl)bis(1H-tetra­zol-1-ido-κN (1))]copper(II)
title_fullStr Tetra­kis(dimethyl­ammonium) trans-di­chloridobis[5,5′-(pyrazine-2,3-diyl)bis(1H-tetra­zol-1-ido-κN (1))]copper(II)
title_full_unstemmed Tetra­kis(dimethyl­ammonium) trans-di­chloridobis[5,5′-(pyrazine-2,3-diyl)bis(1H-tetra­zol-1-ido-κN (1))]copper(II)
title_short Tetra­kis(dimethyl­ammonium) trans-di­chloridobis[5,5′-(pyrazine-2,3-diyl)bis(1H-tetra­zol-1-ido-κN (1))]copper(II)
title_sort tetra­kis(dimethyl­ammonium) trans-di­chloridobis[5,5′-(pyrazine-2,3-diyl)bis(1h-tetra­zol-1-ido-κn (1))]copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470127/
https://www.ncbi.nlm.nih.gov/pubmed/23125571
http://dx.doi.org/10.1107/S1600536812036896
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