Cargando…
Bis(methanol-κO)bis(1,2-diamino-2-hydroxyiminoethanone oximato-κ(2) N,N′)copper(II) bis(oxamide dioxime) methanol disolvate
In the title compound, [Cu(C(2)H(5)N(4)O(2))(2)(CH(3)OH)(2)]·2C(2)H(6)N(4)O(2)·2CH(3)OH, the Cu(II) atom, lying on an inversion center, is coordinated by four N atoms from two 1,2-diamino-2-hydroxyiminoethanone oximate anion and two O atoms from two methanol molecules in a distorted octahedral...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470128/ https://www.ncbi.nlm.nih.gov/pubmed/23125572 http://dx.doi.org/10.1107/S1600536812036811 |
Sumario: | In the title compound, [Cu(C(2)H(5)N(4)O(2))(2)(CH(3)OH)(2)]·2C(2)H(6)N(4)O(2)·2CH(3)OH, the Cu(II) atom, lying on an inversion center, is coordinated by four N atoms from two 1,2-diamino-2-hydroxyiminoethanone oximate anion and two O atoms from two methanol molecules in a distorted octahedral geometry. The two uncoordinating oxamide dioxime molecules, each lying on an inversion center, adopt a trans conformation. In the crystal, O—H⋯O, N—H⋯O and N—H⋯N hydrogen bonds link the complex molecules and the oxamide dioxime and methanol molecules. |
---|