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Bis(methanol-κO)bis­(1,2-diamino-2-hy­droxy­imino­ethanone oximato-κ(2) N,N′)copper(II) bis­(oxamide dioxime) methanol disolvate

In the title compound, [Cu(C(2)H(5)N(4)O(2))(2)(CH(3)OH)(2)]·2C(2)H(6)N(4)O(2)·2CH(3)OH, the Cu(II) atom, lying on an inversion center, is coordinated by four N atoms from two 1,2-diamino-2-hy­droxy­imino­ethanone oximate anion and two O atoms from two methanol mol­ecules in a distorted octa­hedral...

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Detalles Bibliográficos
Autores principales: Liu, Daying, Zhang, Ruihong, Hu, Hui, Qi, Jing, Yang, Guangming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470128/
https://www.ncbi.nlm.nih.gov/pubmed/23125572
http://dx.doi.org/10.1107/S1600536812036811
Descripción
Sumario:In the title compound, [Cu(C(2)H(5)N(4)O(2))(2)(CH(3)OH)(2)]·2C(2)H(6)N(4)O(2)·2CH(3)OH, the Cu(II) atom, lying on an inversion center, is coordinated by four N atoms from two 1,2-diamino-2-hy­droxy­imino­ethanone oximate anion and two O atoms from two methanol mol­ecules in a distorted octa­hedral geometry. The two uncoordinating oxamide dioxime mol­ecules, each lying on an inversion center, adopt a trans conformation. In the crystal, O—H⋯O, N—H⋯O and N—H⋯N hydrogen bonds link the complex mol­ecules and the oxamide dioxime and methanol mol­ecules.