Bis(methanol-κO)bis­(1,2-diamino-2-hy­droxy­imino­ethanone oximato-κ(2) N,N′)copper(II) bis­(oxamide dioxime) methanol disolvate

In the title compound, [Cu(C(2)H(5)N(4)O(2))(2)(CH(3)OH)(2)]·2C(2)H(6)N(4)O(2)·2CH(3)OH, the Cu(II) atom, lying on an inversion center, is coordinated by four N atoms from two 1,2-diamino-2-hy­droxy­imino­ethanone oximate anion and two O atoms from two methanol mol­ecules in a distorted octa­hedral...

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Detalles Bibliográficos
Autores principales: Liu, Daying, Zhang, Ruihong, Hu, Hui, Qi, Jing, Yang, Guangming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470128/
https://www.ncbi.nlm.nih.gov/pubmed/23125572
http://dx.doi.org/10.1107/S1600536812036811
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author Liu, Daying
Zhang, Ruihong
Hu, Hui
Qi, Jing
Yang, Guangming
author_facet Liu, Daying
Zhang, Ruihong
Hu, Hui
Qi, Jing
Yang, Guangming
author_sort Liu, Daying
collection PubMed
description In the title compound, [Cu(C(2)H(5)N(4)O(2))(2)(CH(3)OH)(2)]·2C(2)H(6)N(4)O(2)·2CH(3)OH, the Cu(II) atom, lying on an inversion center, is coordinated by four N atoms from two 1,2-diamino-2-hy­droxy­imino­ethanone oximate anion and two O atoms from two methanol mol­ecules in a distorted octa­hedral geometry. The two uncoordinating oxamide dioxime mol­ecules, each lying on an inversion center, adopt a trans conformation. In the crystal, O—H⋯O, N—H⋯O and N—H⋯N hydrogen bonds link the complex mol­ecules and the oxamide dioxime and methanol mol­ecules.
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spelling pubmed-34701282012-11-02 Bis(methanol-κO)bis­(1,2-diamino-2-hy­droxy­imino­ethanone oximato-κ(2) N,N′)copper(II) bis­(oxamide dioxime) methanol disolvate Liu, Daying Zhang, Ruihong Hu, Hui Qi, Jing Yang, Guangming Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(2)H(5)N(4)O(2))(2)(CH(3)OH)(2)]·2C(2)H(6)N(4)O(2)·2CH(3)OH, the Cu(II) atom, lying on an inversion center, is coordinated by four N atoms from two 1,2-diamino-2-hy­droxy­imino­ethanone oximate anion and two O atoms from two methanol mol­ecules in a distorted octa­hedral geometry. The two uncoordinating oxamide dioxime mol­ecules, each lying on an inversion center, adopt a trans conformation. In the crystal, O—H⋯O, N—H⋯O and N—H⋯N hydrogen bonds link the complex mol­ecules and the oxamide dioxime and methanol mol­ecules. International Union of Crystallography 2012-09-01 /pmc/articles/PMC3470128/ /pubmed/23125572 http://dx.doi.org/10.1107/S1600536812036811 Text en © Liu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Daying
Zhang, Ruihong
Hu, Hui
Qi, Jing
Yang, Guangming
Bis(methanol-κO)bis­(1,2-diamino-2-hy­droxy­imino­ethanone oximato-κ(2) N,N′)copper(II) bis­(oxamide dioxime) methanol disolvate
title Bis(methanol-κO)bis­(1,2-diamino-2-hy­droxy­imino­ethanone oximato-κ(2) N,N′)copper(II) bis­(oxamide dioxime) methanol disolvate
title_full Bis(methanol-κO)bis­(1,2-diamino-2-hy­droxy­imino­ethanone oximato-κ(2) N,N′)copper(II) bis­(oxamide dioxime) methanol disolvate
title_fullStr Bis(methanol-κO)bis­(1,2-diamino-2-hy­droxy­imino­ethanone oximato-κ(2) N,N′)copper(II) bis­(oxamide dioxime) methanol disolvate
title_full_unstemmed Bis(methanol-κO)bis­(1,2-diamino-2-hy­droxy­imino­ethanone oximato-κ(2) N,N′)copper(II) bis­(oxamide dioxime) methanol disolvate
title_short Bis(methanol-κO)bis­(1,2-diamino-2-hy­droxy­imino­ethanone oximato-κ(2) N,N′)copper(II) bis­(oxamide dioxime) methanol disolvate
title_sort bis(methanol-κo)bis­(1,2-diamino-2-hy­droxy­imino­ethanone oximato-κ(2) n,n′)copper(ii) bis­(oxamide dioxime) methanol disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470128/
https://www.ncbi.nlm.nih.gov/pubmed/23125572
http://dx.doi.org/10.1107/S1600536812036811
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