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Poly[μ(3)-aqua-aqua(μ(3)-3,5-dinitrobenzoato-κO (1):O (3):O (5))caesium]
In the structure of the title complex, [Cs(C(7)H(3)N(2)O(6))(H(2)O)(2)](n), the Cs salt of 3,5-dinitrobenzoic acid, the metal complex centres have have irregular CsO(8) coordination, comprising two water molecules (one triply bridging and the other monodentate) and four O-atom donors from two nitr...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470131/ https://www.ncbi.nlm.nih.gov/pubmed/23125575 http://dx.doi.org/10.1107/S1600536812037130 |
Sumario: | In the structure of the title complex, [Cs(C(7)H(3)N(2)O(6))(H(2)O)(2)](n), the Cs salt of 3,5-dinitrobenzoic acid, the metal complex centres have have irregular CsO(8) coordination, comprising two water molecules (one triply bridging and the other monodentate) and four O-atom donors from two nitro groups and one bridging carboxylate O-atom donor from the ligand. Intra-unit O—H⋯O hydrogen-bonding interactions involving both water molecules are observed in the three-dimensional polymeric complex structure. |
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