Poly[μ(3)-aqua-aqua(μ(3)-3,5-dinitro­benzoato-κO (1):O (3):O (5))caesium]

In the structure of the title complex, [Cs(C(7)H(3)N(2)O(6))(H(2)O)(2)](n), the Cs salt of 3,5-dinitro­benzoic acid, the metal complex centres have have irregular CsO(8) coordination, comprising two water mol­ecules (one triply bridging and the other monodentate) and four O-atom donors from two nitr...

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Detalles Bibliográficos
Autor principal: Smith, Graham
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470131/
https://www.ncbi.nlm.nih.gov/pubmed/23125575
http://dx.doi.org/10.1107/S1600536812037130
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author Smith, Graham
author_facet Smith, Graham
author_sort Smith, Graham
collection PubMed
description In the structure of the title complex, [Cs(C(7)H(3)N(2)O(6))(H(2)O)(2)](n), the Cs salt of 3,5-dinitro­benzoic acid, the metal complex centres have have irregular CsO(8) coordination, comprising two water mol­ecules (one triply bridging and the other monodentate) and four O-atom donors from two nitro groups and one bridging carboxyl­ate O-atom donor from the ligand. Intra-unit O—H⋯O hydrogen-bonding inter­actions involving both water mol­ecules are observed in the three-dimensional polymeric complex structure.
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spelling pubmed-34701312012-11-02 Poly[μ(3)-aqua-aqua(μ(3)-3,5-dinitro­benzoato-κO (1):O (3):O (5))caesium] Smith, Graham Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of the title complex, [Cs(C(7)H(3)N(2)O(6))(H(2)O)(2)](n), the Cs salt of 3,5-dinitro­benzoic acid, the metal complex centres have have irregular CsO(8) coordination, comprising two water mol­ecules (one triply bridging and the other monodentate) and four O-atom donors from two nitro groups and one bridging carboxyl­ate O-atom donor from the ligand. Intra-unit O—H⋯O hydrogen-bonding inter­actions involving both water mol­ecules are observed in the three-dimensional polymeric complex structure. International Union of Crystallography 2012-09-05 /pmc/articles/PMC3470131/ /pubmed/23125575 http://dx.doi.org/10.1107/S1600536812037130 Text en © Graham Smith 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Smith, Graham
Poly[μ(3)-aqua-aqua(μ(3)-3,5-dinitro­benzoato-κO (1):O (3):O (5))caesium]
title Poly[μ(3)-aqua-aqua(μ(3)-3,5-dinitro­benzoato-κO (1):O (3):O (5))caesium]
title_full Poly[μ(3)-aqua-aqua(μ(3)-3,5-dinitro­benzoato-κO (1):O (3):O (5))caesium]
title_fullStr Poly[μ(3)-aqua-aqua(μ(3)-3,5-dinitro­benzoato-κO (1):O (3):O (5))caesium]
title_full_unstemmed Poly[μ(3)-aqua-aqua(μ(3)-3,5-dinitro­benzoato-κO (1):O (3):O (5))caesium]
title_short Poly[μ(3)-aqua-aqua(μ(3)-3,5-dinitro­benzoato-κO (1):O (3):O (5))caesium]
title_sort poly[μ(3)-aqua-aqua(μ(3)-3,5-dinitro­benzoato-κo (1):o (3):o (5))caesium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470131/
https://www.ncbi.nlm.nih.gov/pubmed/23125575
http://dx.doi.org/10.1107/S1600536812037130
work_keys_str_mv AT smithgraham polym3aquaaquam335dinitrobenzoatoko1o3o5caesium

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