Guanidinium dioxidobis(picolinato-κ(2) N,O)(picolinato-κO)uranate(VI)

In the title compound, (CH(6)N(3))[U(C(6)H(4)NO(2))(3)O(2)], the uranyl group is coordinated by two O and two N atoms from two chelating picolinate ligands, and one O atom from a third picolinate ligand. The coordination environment of the U(VI) atom (N(2)O(5)) is distorted penta­gonal–bipyramidal....

Descripción completa

Detalles Bibliográficos
Autores principales: Mishkevich, Vitalii I., Grigoriev, Mikhail S., Fedosseev, Alexandre M., Moisy, Philippe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470132/
https://www.ncbi.nlm.nih.gov/pubmed/23125576
http://dx.doi.org/10.1107/S1600536812035465
_version_ 1782246202293616640
author Mishkevich, Vitalii I.
Grigoriev, Mikhail S.
Fedosseev, Alexandre M.
Moisy, Philippe
author_facet Mishkevich, Vitalii I.
Grigoriev, Mikhail S.
Fedosseev, Alexandre M.
Moisy, Philippe
author_sort Mishkevich, Vitalii I.
collection PubMed
description In the title compound, (CH(6)N(3))[U(C(6)H(4)NO(2))(3)O(2)], the uranyl group is coordinated by two O and two N atoms from two chelating picolinate ligands, and one O atom from a third picolinate ligand. The coordination environment of the U(VI) atom (N(2)O(5)) is distorted penta­gonal–bipyramidal. In the crystal, all amino groups are involved in the formation of N—H⋯O and N—H⋯N hydrogen bonds, which link cations and anions into layers parallel to the ac plane.
format Online
Article
Text
id pubmed-3470132
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-34701322012-11-02 Guanidinium dioxidobis(picolinato-κ(2) N,O)(picolinato-κO)uranate(VI) Mishkevich, Vitalii I. Grigoriev, Mikhail S. Fedosseev, Alexandre M. Moisy, Philippe Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (CH(6)N(3))[U(C(6)H(4)NO(2))(3)O(2)], the uranyl group is coordinated by two O and two N atoms from two chelating picolinate ligands, and one O atom from a third picolinate ligand. The coordination environment of the U(VI) atom (N(2)O(5)) is distorted penta­gonal–bipyramidal. In the crystal, all amino groups are involved in the formation of N—H⋯O and N—H⋯N hydrogen bonds, which link cations and anions into layers parallel to the ac plane. International Union of Crystallography 2012-09-05 /pmc/articles/PMC3470132/ /pubmed/23125576 http://dx.doi.org/10.1107/S1600536812035465 Text en © Mishkevich et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Mishkevich, Vitalii I.
Grigoriev, Mikhail S.
Fedosseev, Alexandre M.
Moisy, Philippe
Guanidinium dioxidobis(picolinato-κ(2) N,O)(picolinato-κO)uranate(VI)
title Guanidinium dioxidobis(picolinato-κ(2) N,O)(picolinato-κO)uranate(VI)
title_full Guanidinium dioxidobis(picolinato-κ(2) N,O)(picolinato-κO)uranate(VI)
title_fullStr Guanidinium dioxidobis(picolinato-κ(2) N,O)(picolinato-κO)uranate(VI)
title_full_unstemmed Guanidinium dioxidobis(picolinato-κ(2) N,O)(picolinato-κO)uranate(VI)
title_short Guanidinium dioxidobis(picolinato-κ(2) N,O)(picolinato-κO)uranate(VI)
title_sort guanidinium dioxidobis(picolinato-κ(2) n,o)(picolinato-κo)uranate(vi)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470132/
https://www.ncbi.nlm.nih.gov/pubmed/23125576
http://dx.doi.org/10.1107/S1600536812035465
work_keys_str_mv AT mishkevichvitaliii guanidiniumdioxidobispicolinatok2nopicolinatokouranatevi
AT grigorievmikhails guanidiniumdioxidobispicolinatok2nopicolinatokouranatevi
AT fedosseevalexandrem guanidiniumdioxidobispicolinatok2nopicolinatokouranatevi
AT moisyphilippe guanidiniumdioxidobispicolinatok2nopicolinatokouranatevi

Ejemplares similares