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catena-Poly[[dichloridomercury(II)]-μ-{N-[(E)-pyridin-2-yl­methyl­idene-κN]pyridin-3-amine-κ(2) N (1):N (3)}]

In the title coordination polymer, [HgCl(2)(C(11)H(9)N(3))](n), the Hg(II) ion is coordinated by three N atoms from two N-[(E)-pyridin-2-yl­methyl­idene]pyridin-3-amine (L) ligands and two chloride anions in a distorted trigonal–bipyramidal geometry. The two pyridine rings in L form a dihedral angle...

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Detalles Bibliográficos
Autores principales: Mahmoudi, Ali, Dehghanpour, Saeed, Najafi, Leila, Khalafbeigi, Mohammad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470133/
https://www.ncbi.nlm.nih.gov/pubmed/23125577
http://dx.doi.org/10.1107/S1600536812035775
Descripción
Sumario:In the title coordination polymer, [HgCl(2)(C(11)H(9)N(3))](n), the Hg(II) ion is coordinated by three N atoms from two N-[(E)-pyridin-2-yl­methyl­idene]pyridin-3-amine (L) ligands and two chloride anions in a distorted trigonal–bipyramidal geometry. The two pyridine rings in L form a dihedral angle of 50.0 (2)°. L ligands bridge adjacent HgCl(2) units into polymeric chains propagating in [010]. The crystal packing is further stabilized by weak inter­molecular C—H⋯Cl hydrogen bonds and π–π inter­actions between the pyridine rings, with a centroid–centroid separation of 3.529 (9) Å.