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catena-Poly[[dichloridomercury(II)]-μ-{N-[(E)-pyridin-2-ylmethylidene-κN]pyridin-3-amine-κ(2) N (1):N (3)}]
In the title coordination polymer, [HgCl(2)(C(11)H(9)N(3))](n), the Hg(II) ion is coordinated by three N atoms from two N-[(E)-pyridin-2-ylmethylidene]pyridin-3-amine (L) ligands and two chloride anions in a distorted trigonal–bipyramidal geometry. The two pyridine rings in L form a dihedral angle...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470133/ https://www.ncbi.nlm.nih.gov/pubmed/23125577 http://dx.doi.org/10.1107/S1600536812035775 |
Sumario: | In the title coordination polymer, [HgCl(2)(C(11)H(9)N(3))](n), the Hg(II) ion is coordinated by three N atoms from two N-[(E)-pyridin-2-ylmethylidene]pyridin-3-amine (L) ligands and two chloride anions in a distorted trigonal–bipyramidal geometry. The two pyridine rings in L form a dihedral angle of 50.0 (2)°. L ligands bridge adjacent HgCl(2) units into polymeric chains propagating in [010]. The crystal packing is further stabilized by weak intermolecular C—H⋯Cl hydrogen bonds and π–π interactions between the pyridine rings, with a centroid–centroid separation of 3.529 (9) Å. |
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