catena-Poly[[dichloridomercury(II)]-μ-{N-[(E)-pyridin-2-yl­methyl­idene-κN]pyridin-3-amine-κ(2) N (1):N (3)}]

In the title coordination polymer, [HgCl(2)(C(11)H(9)N(3))](n), the Hg(II) ion is coordinated by three N atoms from two N-[(E)-pyridin-2-yl­methyl­idene]pyridin-3-amine (L) ligands and two chloride anions in a distorted trigonal–bipyramidal geometry. The two pyridine rings in L form a dihedral angle...

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Autores principales: Mahmoudi, Ali, Dehghanpour, Saeed, Najafi, Leila, Khalafbeigi, Mohammad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470133/
https://www.ncbi.nlm.nih.gov/pubmed/23125577
http://dx.doi.org/10.1107/S1600536812035775
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author Mahmoudi, Ali
Dehghanpour, Saeed
Najafi, Leila
Khalafbeigi, Mohammad
author_facet Mahmoudi, Ali
Dehghanpour, Saeed
Najafi, Leila
Khalafbeigi, Mohammad
author_sort Mahmoudi, Ali
collection PubMed
description In the title coordination polymer, [HgCl(2)(C(11)H(9)N(3))](n), the Hg(II) ion is coordinated by three N atoms from two N-[(E)-pyridin-2-yl­methyl­idene]pyridin-3-amine (L) ligands and two chloride anions in a distorted trigonal–bipyramidal geometry. The two pyridine rings in L form a dihedral angle of 50.0 (2)°. L ligands bridge adjacent HgCl(2) units into polymeric chains propagating in [010]. The crystal packing is further stabilized by weak inter­molecular C—H⋯Cl hydrogen bonds and π–π inter­actions between the pyridine rings, with a centroid–centroid separation of 3.529 (9) Å.
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spelling pubmed-34701332012-11-02 catena-Poly[[dichloridomercury(II)]-μ-{N-[(E)-pyridin-2-yl­methyl­idene-κN]pyridin-3-amine-κ(2) N (1):N (3)}] Mahmoudi, Ali Dehghanpour, Saeed Najafi, Leila Khalafbeigi, Mohammad Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, [HgCl(2)(C(11)H(9)N(3))](n), the Hg(II) ion is coordinated by three N atoms from two N-[(E)-pyridin-2-yl­methyl­idene]pyridin-3-amine (L) ligands and two chloride anions in a distorted trigonal–bipyramidal geometry. The two pyridine rings in L form a dihedral angle of 50.0 (2)°. L ligands bridge adjacent HgCl(2) units into polymeric chains propagating in [010]. The crystal packing is further stabilized by weak inter­molecular C—H⋯Cl hydrogen bonds and π–π inter­actions between the pyridine rings, with a centroid–centroid separation of 3.529 (9) Å. International Union of Crystallography 2012-09-05 /pmc/articles/PMC3470133/ /pubmed/23125577 http://dx.doi.org/10.1107/S1600536812035775 Text en © Mahmoudi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Mahmoudi, Ali
Dehghanpour, Saeed
Najafi, Leila
Khalafbeigi, Mohammad
catena-Poly[[dichloridomercury(II)]-μ-{N-[(E)-pyridin-2-yl­methyl­idene-κN]pyridin-3-amine-κ(2) N (1):N (3)}]
title catena-Poly[[dichloridomercury(II)]-μ-{N-[(E)-pyridin-2-yl­methyl­idene-κN]pyridin-3-amine-κ(2) N (1):N (3)}]
title_full catena-Poly[[dichloridomercury(II)]-μ-{N-[(E)-pyridin-2-yl­methyl­idene-κN]pyridin-3-amine-κ(2) N (1):N (3)}]
title_fullStr catena-Poly[[dichloridomercury(II)]-μ-{N-[(E)-pyridin-2-yl­methyl­idene-κN]pyridin-3-amine-κ(2) N (1):N (3)}]
title_full_unstemmed catena-Poly[[dichloridomercury(II)]-μ-{N-[(E)-pyridin-2-yl­methyl­idene-κN]pyridin-3-amine-κ(2) N (1):N (3)}]
title_short catena-Poly[[dichloridomercury(II)]-μ-{N-[(E)-pyridin-2-yl­methyl­idene-κN]pyridin-3-amine-κ(2) N (1):N (3)}]
title_sort catena-poly[[dichloridomercury(ii)]-μ-{n-[(e)-pyridin-2-yl­methyl­idene-κn]pyridin-3-amine-κ(2) n (1):n (3)}]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470133/
https://www.ncbi.nlm.nih.gov/pubmed/23125577
http://dx.doi.org/10.1107/S1600536812035775
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