Diaqua­bis­(1H-imidazole-4-carboxyl­ato-κ(2) N (3),O)cobalt(II)

In the title compound, [Co(C(4)H(3)N(2)O(2))(2)(H(2)O)(2)], the Co(II) ion is located on a twofold rotation axis and shows a distorted octa­hedral coordination configuration, defined by two N,O-bidentate 1H-imidazole-4-carboxyl­ate ligands in the equatorial plane and two water mol­ecules in the axia...

Descripción completa

Detalles Bibliográficos
Autor principal: Chen, Wen-Sen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470135/
https://www.ncbi.nlm.nih.gov/pubmed/23125579
http://dx.doi.org/10.1107/S1600536812037579
_version_ 1782246203012939776
author Chen, Wen-Sen
author_facet Chen, Wen-Sen
author_sort Chen, Wen-Sen
collection PubMed
description In the title compound, [Co(C(4)H(3)N(2)O(2))(2)(H(2)O)(2)], the Co(II) ion is located on a twofold rotation axis and shows a distorted octa­hedral coordination configuration, defined by two N,O-bidentate 1H-imidazole-4-carboxyl­ate ligands in the equatorial plane and two water mol­ecules in the axial positions. In the crystal, O—H⋯O and N—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional supra­molecular network. π–π stacking inter­actions between the imidazole rings [centroid–centroid distances = 3.4914 (15) and 3.6167 (15) Å] further stabilize the crystal structure.
format Online
Article
Text
id pubmed-3470135
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-34701352012-11-02 Diaqua­bis­(1H-imidazole-4-carboxyl­ato-κ(2) N (3),O)cobalt(II) Chen, Wen-Sen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(4)H(3)N(2)O(2))(2)(H(2)O)(2)], the Co(II) ion is located on a twofold rotation axis and shows a distorted octa­hedral coordination configuration, defined by two N,O-bidentate 1H-imidazole-4-carboxyl­ate ligands in the equatorial plane and two water mol­ecules in the axial positions. In the crystal, O—H⋯O and N—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional supra­molecular network. π–π stacking inter­actions between the imidazole rings [centroid–centroid distances = 3.4914 (15) and 3.6167 (15) Å] further stabilize the crystal structure. International Union of Crystallography 2012-09-08 /pmc/articles/PMC3470135/ /pubmed/23125579 http://dx.doi.org/10.1107/S1600536812037579 Text en © Wen-Sen Chen 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chen, Wen-Sen
Diaqua­bis­(1H-imidazole-4-carboxyl­ato-κ(2) N (3),O)cobalt(II)
title Diaqua­bis­(1H-imidazole-4-carboxyl­ato-κ(2) N (3),O)cobalt(II)
title_full Diaqua­bis­(1H-imidazole-4-carboxyl­ato-κ(2) N (3),O)cobalt(II)
title_fullStr Diaqua­bis­(1H-imidazole-4-carboxyl­ato-κ(2) N (3),O)cobalt(II)
title_full_unstemmed Diaqua­bis­(1H-imidazole-4-carboxyl­ato-κ(2) N (3),O)cobalt(II)
title_short Diaqua­bis­(1H-imidazole-4-carboxyl­ato-κ(2) N (3),O)cobalt(II)
title_sort diaqua­bis­(1h-imidazole-4-carboxyl­ato-κ(2) n (3),o)cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470135/
https://www.ncbi.nlm.nih.gov/pubmed/23125579
http://dx.doi.org/10.1107/S1600536812037579
work_keys_str_mv AT chenwensen diaquabis1himidazole4carboxylatok2n3ocobaltii

Ejemplares similares