Bis[(1,1′-biphenyl-2,2′-di­yl)di-tert-butyl­phospho­nium] di-μ-chlorido-bis­[dichlorido­palladate(II)]

In the title compound, (C(20)H(26)P)(2)[Pd(2)Cl(6)], the Pd(II) atom within the hexachloridodipalladate(II) dianion has a square-planar geometry. It resides on a centre of inversion with the asymmetric unit containing half of the dianion and one phospho­nium cation. Only weak C—H⋯π inter­actions are...

Descripción completa

Detalles Bibliográficos
Autores principales: Arderne, Charmaine, Holzapfel, Cedric W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470136/
https://www.ncbi.nlm.nih.gov/pubmed/23125580
http://dx.doi.org/10.1107/S1600536812037786
Descripción
Sumario:In the title compound, (C(20)H(26)P)(2)[Pd(2)Cl(6)], the Pd(II) atom within the hexachloridodipalladate(II) dianion has a square-planar geometry. It resides on a centre of inversion with the asymmetric unit containing half of the dianion and one phospho­nium cation. Only weak C—H⋯π inter­actions are present in the crystal structure.

Ejemplares similares