Bis[(1,1′-biphenyl-2,2′-di­yl)di-tert-butyl­phospho­nium] di-μ-chlorido-bis­[dichlorido­palladate(II)]

In the title compound, (C(20)H(26)P)(2)[Pd(2)Cl(6)], the Pd(II) atom within the hexachloridodipalladate(II) dianion has a square-planar geometry. It resides on a centre of inversion with the asymmetric unit containing half of the dianion and one phospho­nium cation. Only weak C—H⋯π inter­actions are...

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Detalles Bibliográficos
Autores principales: Arderne, Charmaine, Holzapfel, Cedric W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470136/
https://www.ncbi.nlm.nih.gov/pubmed/23125580
http://dx.doi.org/10.1107/S1600536812037786
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author Arderne, Charmaine
Holzapfel, Cedric W.
author_facet Arderne, Charmaine
Holzapfel, Cedric W.
author_sort Arderne, Charmaine
collection PubMed
description In the title compound, (C(20)H(26)P)(2)[Pd(2)Cl(6)], the Pd(II) atom within the hexachloridodipalladate(II) dianion has a square-planar geometry. It resides on a centre of inversion with the asymmetric unit containing half of the dianion and one phospho­nium cation. Only weak C—H⋯π inter­actions are present in the crystal structure.
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spelling pubmed-34701362012-11-02 Bis[(1,1′-biphenyl-2,2′-di­yl)di-tert-butyl­phospho­nium] di-μ-chlorido-bis­[dichlorido­palladate(II)] Arderne, Charmaine Holzapfel, Cedric W. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(20)H(26)P)(2)[Pd(2)Cl(6)], the Pd(II) atom within the hexachloridodipalladate(II) dianion has a square-planar geometry. It resides on a centre of inversion with the asymmetric unit containing half of the dianion and one phospho­nium cation. Only weak C—H⋯π inter­actions are present in the crystal structure. International Union of Crystallography 2012-09-08 /pmc/articles/PMC3470136/ /pubmed/23125580 http://dx.doi.org/10.1107/S1600536812037786 Text en © Arderne and Holzapfel 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Arderne, Charmaine
Holzapfel, Cedric W.
Bis[(1,1′-biphenyl-2,2′-di­yl)di-tert-butyl­phospho­nium] di-μ-chlorido-bis­[dichlorido­palladate(II)]
title Bis[(1,1′-biphenyl-2,2′-di­yl)di-tert-butyl­phospho­nium] di-μ-chlorido-bis­[dichlorido­palladate(II)]
title_full Bis[(1,1′-biphenyl-2,2′-di­yl)di-tert-butyl­phospho­nium] di-μ-chlorido-bis­[dichlorido­palladate(II)]
title_fullStr Bis[(1,1′-biphenyl-2,2′-di­yl)di-tert-butyl­phospho­nium] di-μ-chlorido-bis­[dichlorido­palladate(II)]
title_full_unstemmed Bis[(1,1′-biphenyl-2,2′-di­yl)di-tert-butyl­phospho­nium] di-μ-chlorido-bis­[dichlorido­palladate(II)]
title_short Bis[(1,1′-biphenyl-2,2′-di­yl)di-tert-butyl­phospho­nium] di-μ-chlorido-bis­[dichlorido­palladate(II)]
title_sort bis[(1,1′-biphenyl-2,2′-di­yl)di-tert-butyl­phospho­nium] di-μ-chlorido-bis­[dichlorido­palladate(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470136/
https://www.ncbi.nlm.nih.gov/pubmed/23125580
http://dx.doi.org/10.1107/S1600536812037786
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