(Acetato-κO){bis­[(2,4-dimethyl-1H-pyrazol-1-yl)meth­yl][(pyridin-2-yl)meth­yl]amine}­cobalt(II) hexa­fluorido­phosphate

In the title compound, [Co(CH(3)CO(2))(C(18)H(24)N(6))]PF(6), the Co(II) atom is penta­coordinated in a distorted trigonal–bipyramidal geometry by four N atoms from a tripodal ligand and one O atom from a monodentate acetate ligand. The crystal packing is stabilized by inter­molecular C—H⋯F and C—H⋯...

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Detalles Bibliográficos
Autor principal: Yu, Fan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470138/
https://www.ncbi.nlm.nih.gov/pubmed/23125582
http://dx.doi.org/10.1107/S1600536812035222
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author Yu, Fan
author_facet Yu, Fan
author_sort Yu, Fan
collection PubMed
description In the title compound, [Co(CH(3)CO(2))(C(18)H(24)N(6))]PF(6), the Co(II) atom is penta­coordinated in a distorted trigonal–bipyramidal geometry by four N atoms from a tripodal ligand and one O atom from a monodentate acetate ligand. The crystal packing is stabilized by inter­molecular C—H⋯F and C—H⋯O hydrogen bonds.
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spelling pubmed-34701382012-11-02 (Acetato-κO){bis­[(2,4-dimethyl-1H-pyrazol-1-yl)meth­yl][(pyridin-2-yl)meth­yl]amine}­cobalt(II) hexa­fluorido­phosphate Yu, Fan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(CH(3)CO(2))(C(18)H(24)N(6))]PF(6), the Co(II) atom is penta­coordinated in a distorted trigonal–bipyramidal geometry by four N atoms from a tripodal ligand and one O atom from a monodentate acetate ligand. The crystal packing is stabilized by inter­molecular C—H⋯F and C—H⋯O hydrogen bonds. International Union of Crystallography 2012-09-08 /pmc/articles/PMC3470138/ /pubmed/23125582 http://dx.doi.org/10.1107/S1600536812035222 Text en © Fan Yu 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yu, Fan
(Acetato-κO){bis­[(2,4-dimethyl-1H-pyrazol-1-yl)meth­yl][(pyridin-2-yl)meth­yl]amine}­cobalt(II) hexa­fluorido­phosphate
title (Acetato-κO){bis­[(2,4-dimethyl-1H-pyrazol-1-yl)meth­yl][(pyridin-2-yl)meth­yl]amine}­cobalt(II) hexa­fluorido­phosphate
title_full (Acetato-κO){bis­[(2,4-dimethyl-1H-pyrazol-1-yl)meth­yl][(pyridin-2-yl)meth­yl]amine}­cobalt(II) hexa­fluorido­phosphate
title_fullStr (Acetato-κO){bis­[(2,4-dimethyl-1H-pyrazol-1-yl)meth­yl][(pyridin-2-yl)meth­yl]amine}­cobalt(II) hexa­fluorido­phosphate
title_full_unstemmed (Acetato-κO){bis­[(2,4-dimethyl-1H-pyrazol-1-yl)meth­yl][(pyridin-2-yl)meth­yl]amine}­cobalt(II) hexa­fluorido­phosphate
title_short (Acetato-κO){bis­[(2,4-dimethyl-1H-pyrazol-1-yl)meth­yl][(pyridin-2-yl)meth­yl]amine}­cobalt(II) hexa­fluorido­phosphate
title_sort (acetato-κo){bis­[(2,4-dimethyl-1h-pyrazol-1-yl)meth­yl][(pyridin-2-yl)meth­yl]amine}­cobalt(ii) hexa­fluorido­phosphate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470138/
https://www.ncbi.nlm.nih.gov/pubmed/23125582
http://dx.doi.org/10.1107/S1600536812035222
work_keys_str_mv AT yufan acetatokobis24dimethyl1hpyrazol1ylmethylpyridin2ylmethylaminecobaltiihexafluoridophosphate

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