Dichlorido[2-(pyridin-2-yl)-N-(pyridin-2-yl­methyl­idene)ethanamine-κ(3) N,N′,N′′]manganese(II) monohydrate

In the title complex, [MnCl(2)(C(13)H(13)N(3))]·H(2)O, the Mn(II) atom is in a distorted square-pyramidal environment, with an Addison τ parameter of 0.037. The coordination geometry is defined by three N-atom donors from the tridentate 2-(pyridin-2-yl)-N-(pyridin-2-yl­methyl­idene)ethanamine ligand...

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Autores principales: Tinguiano, Daniel, Thiam, Ibrahima Elhadj, Dieng, Moussa, Gaye, Mohamed, Retailleau, Pascal
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470139/
https://www.ncbi.nlm.nih.gov/pubmed/23125583
http://dx.doi.org/10.1107/S1600536812037877
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author Tinguiano, Daniel
Thiam, Ibrahima Elhadj
Dieng, Moussa
Gaye, Mohamed
Retailleau, Pascal
author_facet Tinguiano, Daniel
Thiam, Ibrahima Elhadj
Dieng, Moussa
Gaye, Mohamed
Retailleau, Pascal
author_sort Tinguiano, Daniel
collection PubMed
description In the title complex, [MnCl(2)(C(13)H(13)N(3))]·H(2)O, the Mn(II) atom is in a distorted square-pyramidal environment, with an Addison τ parameter of 0.037. The coordination geometry is defined by three N-atom donors from the tridentate 2-(pyridin-2-yl)-N-(pyridin-2-yl­methyl­idene)ethanamine ligand and two terminal Cl atoms. Although the H atoms of the lattice water molecule were not located, O⋯O distances of 3.103 (7) Å and O⋯Cl distances of 3.240 (3) and 3.482 (4) Å suggest that hydrogen bonding is responsible for the stabilization of the crystal packing.
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spelling pubmed-34701392012-11-02 Dichlorido[2-(pyridin-2-yl)-N-(pyridin-2-yl­methyl­idene)ethanamine-κ(3) N,N′,N′′]manganese(II) monohydrate Tinguiano, Daniel Thiam, Ibrahima Elhadj Dieng, Moussa Gaye, Mohamed Retailleau, Pascal Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [MnCl(2)(C(13)H(13)N(3))]·H(2)O, the Mn(II) atom is in a distorted square-pyramidal environment, with an Addison τ parameter of 0.037. The coordination geometry is defined by three N-atom donors from the tridentate 2-(pyridin-2-yl)-N-(pyridin-2-yl­methyl­idene)ethanamine ligand and two terminal Cl atoms. Although the H atoms of the lattice water molecule were not located, O⋯O distances of 3.103 (7) Å and O⋯Cl distances of 3.240 (3) and 3.482 (4) Å suggest that hydrogen bonding is responsible for the stabilization of the crystal packing. International Union of Crystallography 2012-09-08 /pmc/articles/PMC3470139/ /pubmed/23125583 http://dx.doi.org/10.1107/S1600536812037877 Text en © Tinguiano et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tinguiano, Daniel
Thiam, Ibrahima Elhadj
Dieng, Moussa
Gaye, Mohamed
Retailleau, Pascal
Dichlorido[2-(pyridin-2-yl)-N-(pyridin-2-yl­methyl­idene)ethanamine-κ(3) N,N′,N′′]manganese(II) monohydrate
title Dichlorido[2-(pyridin-2-yl)-N-(pyridin-2-yl­methyl­idene)ethanamine-κ(3) N,N′,N′′]manganese(II) monohydrate
title_full Dichlorido[2-(pyridin-2-yl)-N-(pyridin-2-yl­methyl­idene)ethanamine-κ(3) N,N′,N′′]manganese(II) monohydrate
title_fullStr Dichlorido[2-(pyridin-2-yl)-N-(pyridin-2-yl­methyl­idene)ethanamine-κ(3) N,N′,N′′]manganese(II) monohydrate
title_full_unstemmed Dichlorido[2-(pyridin-2-yl)-N-(pyridin-2-yl­methyl­idene)ethanamine-κ(3) N,N′,N′′]manganese(II) monohydrate
title_short Dichlorido[2-(pyridin-2-yl)-N-(pyridin-2-yl­methyl­idene)ethanamine-κ(3) N,N′,N′′]manganese(II) monohydrate
title_sort dichlorido[2-(pyridin-2-yl)-n-(pyridin-2-yl­methyl­idene)ethanamine-κ(3) n,n′,n′′]manganese(ii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470139/
https://www.ncbi.nlm.nih.gov/pubmed/23125583
http://dx.doi.org/10.1107/S1600536812037877
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