Cargando…
{4,4′,6,6′-Tetrachloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}dioxidomolybdenum(VI)
The asymmetric unit of the title compound, [Mo(C(19)H(16)Cl(4)N(2)O(2))O(2)], comprises two independent molecules (A and B). The geometry around the Mo(VI) atom is distorted octahedral in each complex molecule, supported by two oxide O atoms and the N(2)O(2) donor atoms of the coordinating ligand...
Autores principales: | , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470140/ https://www.ncbi.nlm.nih.gov/pubmed/23125584 http://dx.doi.org/10.1107/S160053681203807X |
_version_ | 1782246204217753600 |
---|---|
author | Kargar, Hadi Kubicki, Maciej |
author_facet | Kargar, Hadi Kubicki, Maciej |
author_sort | Kargar, Hadi |
collection | PubMed |
description | The asymmetric unit of the title compound, [Mo(C(19)H(16)Cl(4)N(2)O(2))O(2)], comprises two independent molecules (A and B). The geometry around the Mo(VI) atom is distorted octahedral in each complex molecule, supported by two oxide O atoms and the N(2)O(2) donor atoms of the coordinating ligand. The dihedral angle between the benzene rings is 74.96 (11) Å for molecule A and 76.05 (11) Å for molecule B. In the crystal, the B molecules are linked by pairs of C—H⋯Cl hydrogen bonds, forming inversion dimers. The crystal structure is further stabilized by C—H⋯π interactions. An interesting feature of the crystal structure is a Cl⋯Cl contact [3.3748 (18) Å], which is shorter than the sum of the van der Waals radii of Cl atoms (3.50 Å). |
format | Online Article Text |
id | pubmed-3470140 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34701402012-11-02 {4,4′,6,6′-Tetrachloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}dioxidomolybdenum(VI) Kargar, Hadi Kubicki, Maciej Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Mo(C(19)H(16)Cl(4)N(2)O(2))O(2)], comprises two independent molecules (A and B). The geometry around the Mo(VI) atom is distorted octahedral in each complex molecule, supported by two oxide O atoms and the N(2)O(2) donor atoms of the coordinating ligand. The dihedral angle between the benzene rings is 74.96 (11) Å for molecule A and 76.05 (11) Å for molecule B. In the crystal, the B molecules are linked by pairs of C—H⋯Cl hydrogen bonds, forming inversion dimers. The crystal structure is further stabilized by C—H⋯π interactions. An interesting feature of the crystal structure is a Cl⋯Cl contact [3.3748 (18) Å], which is shorter than the sum of the van der Waals radii of Cl atoms (3.50 Å). International Union of Crystallography 2012-09-08 /pmc/articles/PMC3470140/ /pubmed/23125584 http://dx.doi.org/10.1107/S160053681203807X Text en © Kargar and Kubicki 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Kargar, Hadi Kubicki, Maciej {4,4′,6,6′-Tetrachloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}dioxidomolybdenum(VI) |
title | {4,4′,6,6′-Tetrachloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}dioxidomolybdenum(VI) |
title_full | {4,4′,6,6′-Tetrachloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}dioxidomolybdenum(VI) |
title_fullStr | {4,4′,6,6′-Tetrachloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}dioxidomolybdenum(VI) |
title_full_unstemmed | {4,4′,6,6′-Tetrachloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}dioxidomolybdenum(VI) |
title_short | {4,4′,6,6′-Tetrachloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}dioxidomolybdenum(VI) |
title_sort | {4,4′,6,6′-tetrachloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}dioxidomolybdenum(vi) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470140/ https://www.ncbi.nlm.nih.gov/pubmed/23125584 http://dx.doi.org/10.1107/S160053681203807X |
work_keys_str_mv | AT kargarhadi 4466tetrachloro2222dimethylpropane13diylbisnitrilomethanylylidenediphenolatodioxidomolybdenumvi AT kubickimaciej 4466tetrachloro2222dimethylpropane13diylbisnitrilomethanylylidenediphenolatodioxidomolybdenumvi |