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{4,4′-Dimethoxy-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}copper(II) monohydrate
The asymmetric unit of the title compound, [Cu(C(21)H(24)N(2)O(4))]·H(2)O, comprises half of a Schiff base complex and a water molecule. The Cu(II) atom, water molecule and one C atom of the central propylene segment are located on a twofold rotation axis. The geometry around the Cu(II) atom is d...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470142/ https://www.ncbi.nlm.nih.gov/pubmed/23125586 http://dx.doi.org/10.1107/S1600536812038135 |
Sumario: | The asymmetric unit of the title compound, [Cu(C(21)H(24)N(2)O(4))]·H(2)O, comprises half of a Schiff base complex and a water molecule. The Cu(II) atom, water molecule and one C atom of the central propylene segment are located on a twofold rotation axis. The geometry around the Cu(II) atom is distorted square-planar, supported by the N(2)O(2) donor atoms of the coordinating ligand. The dihedral angle between the symmetry-related benzene rings is 42.56 (19)°. In the crystal, O—H⋯O hydrogen bonds involving the water molecule make an R (2) (1)(6) ring motif. Complex molecules are linked into a chain along the c axis via C—H⋯O interactions. |
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