{4,4′-Dimeth­oxy-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}copper(II) monohydrate

The asymmetric unit of the title compound, [Cu(C(21)H(24)N(2)O(4))]·H(2)O, comprises half of a Schiff base complex and a water mol­ecule. The Cu(II) atom, water mol­ecule and one C atom of the central propyl­ene segment are located on a twofold rotation axis. The geometry around the Cu(II) atom is d...

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Autores principales: Ganji, Fatemeh, Kargar, Hadi, Kia, Reza, Mirkhani, Valiollah, Tahir, Muhammad Nawaz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470142/
https://www.ncbi.nlm.nih.gov/pubmed/23125586
http://dx.doi.org/10.1107/S1600536812038135
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author Ganji, Fatemeh
Kargar, Hadi
Kia, Reza
Mirkhani, Valiollah
Tahir, Muhammad Nawaz
author_facet Ganji, Fatemeh
Kargar, Hadi
Kia, Reza
Mirkhani, Valiollah
Tahir, Muhammad Nawaz
author_sort Ganji, Fatemeh
collection PubMed
description The asymmetric unit of the title compound, [Cu(C(21)H(24)N(2)O(4))]·H(2)O, comprises half of a Schiff base complex and a water mol­ecule. The Cu(II) atom, water mol­ecule and one C atom of the central propyl­ene segment are located on a twofold rotation axis. The geometry around the Cu(II) atom is distorted square-planar, supported by the N(2)O(2) donor atoms of the coordinating ligand. The dihedral angle between the symmetry-related benzene rings is 42.56 (19)°. In the crystal, O—H⋯O hydrogen bonds involving the water mol­ecule make an R (2) (1)(6) ring motif. Complex mol­ecules are linked into a chain along the c axis via C—H⋯O inter­actions.
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spelling pubmed-34701422012-11-02 {4,4′-Dimeth­oxy-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}copper(II) monohydrate Ganji, Fatemeh Kargar, Hadi Kia, Reza Mirkhani, Valiollah Tahir, Muhammad Nawaz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Cu(C(21)H(24)N(2)O(4))]·H(2)O, comprises half of a Schiff base complex and a water mol­ecule. The Cu(II) atom, water mol­ecule and one C atom of the central propyl­ene segment are located on a twofold rotation axis. The geometry around the Cu(II) atom is distorted square-planar, supported by the N(2)O(2) donor atoms of the coordinating ligand. The dihedral angle between the symmetry-related benzene rings is 42.56 (19)°. In the crystal, O—H⋯O hydrogen bonds involving the water mol­ecule make an R (2) (1)(6) ring motif. Complex mol­ecules are linked into a chain along the c axis via C—H⋯O inter­actions. International Union of Crystallography 2012-09-12 /pmc/articles/PMC3470142/ /pubmed/23125586 http://dx.doi.org/10.1107/S1600536812038135 Text en © Ganji et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ganji, Fatemeh
Kargar, Hadi
Kia, Reza
Mirkhani, Valiollah
Tahir, Muhammad Nawaz
{4,4′-Dimeth­oxy-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}copper(II) monohydrate
title {4,4′-Dimeth­oxy-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}copper(II) monohydrate
title_full {4,4′-Dimeth­oxy-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}copper(II) monohydrate
title_fullStr {4,4′-Dimeth­oxy-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}copper(II) monohydrate
title_full_unstemmed {4,4′-Dimeth­oxy-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}copper(II) monohydrate
title_short {4,4′-Dimeth­oxy-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}copper(II) monohydrate
title_sort {4,4′-dimeth­oxy-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}copper(ii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470142/
https://www.ncbi.nlm.nih.gov/pubmed/23125586
http://dx.doi.org/10.1107/S1600536812038135
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