Trichlorido(dimethyl sulfoxide-κO)(di-2-pyridyl­amine-κ(2) N,N′)indium(III)

In the title compound, [InCl(3)(C(10)H(9)N(3))(C(2)H(6)OS)], the In(III) atom is six-coordinated in a distorted octa­hedral geometry by two N atoms from a chelating di-2-pyridyl­amine ligand, one O atom from a dimethyl sulfoxide ligand and three Cl atoms. Inter­molecular C—H⋯Cl hydrogen bonds and π–...

Descripción completa

Detalles Bibliográficos
Autores principales: Shirvan, Sadif A., Haydari Dezfuli, Sara, Golabi, Elyas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470143/
https://www.ncbi.nlm.nih.gov/pubmed/23125587
http://dx.doi.org/10.1107/S1600536812038147
Descripción
Sumario:In the title compound, [InCl(3)(C(10)H(9)N(3))(C(2)H(6)OS)], the In(III) atom is six-coordinated in a distorted octa­hedral geometry by two N atoms from a chelating di-2-pyridyl­amine ligand, one O atom from a dimethyl sulfoxide ligand and three Cl atoms. Inter­molecular C—H⋯Cl hydrogen bonds and π–π contacts between the pyridine rings [centroid–centroid distance = 3.510 (3) Å] are present in the crystal.

Ejemplares similares