(Acetato-κ(2) O,O′)(acetato-κO)bis(2-amino-3-methyl­pyridine-κN (1))cobalt(II)

In the title compound, [Co(CH(3)COO)(2)(C(6)H(8)N(2))(2)], the Co(II) ion is five-coordinated by two pyridine N atoms from two 2-amino-3-methyl­pyridine ligands, two O atoms from one acetate ion and one O atom from another acetate ion in a distorted trigonal–bipyramidal geometry. The pyridine rings...

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Detalles Bibliográficos
Autores principales: Tadjarodi, Azadeh, Bijanzad, Keyvan, Notash, Behrouz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470146/
https://www.ncbi.nlm.nih.gov/pubmed/23125590
http://dx.doi.org/10.1107/S1600536812038664
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author Tadjarodi, Azadeh
Bijanzad, Keyvan
Notash, Behrouz
author_facet Tadjarodi, Azadeh
Bijanzad, Keyvan
Notash, Behrouz
author_sort Tadjarodi, Azadeh
collection PubMed
description In the title compound, [Co(CH(3)COO)(2)(C(6)H(8)N(2))(2)], the Co(II) ion is five-coordinated by two pyridine N atoms from two 2-amino-3-methyl­pyridine ligands, two O atoms from one acetate ion and one O atom from another acetate ion in a distorted trigonal–bipyramidal geometry. The pyridine rings are nearly perpendicular to each other [dihedral angle = 84.49 (16)°]. The crystal packing is stabilized by intra­molecular and inter­molecular N—H⋯O hydrogen-bonding inter­actions.
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spelling pubmed-34701462012-11-02 (Acetato-κ(2) O,O′)(acetato-κO)bis(2-amino-3-methyl­pyridine-κN (1))cobalt(II) Tadjarodi, Azadeh Bijanzad, Keyvan Notash, Behrouz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(CH(3)COO)(2)(C(6)H(8)N(2))(2)], the Co(II) ion is five-coordinated by two pyridine N atoms from two 2-amino-3-methyl­pyridine ligands, two O atoms from one acetate ion and one O atom from another acetate ion in a distorted trigonal–bipyramidal geometry. The pyridine rings are nearly perpendicular to each other [dihedral angle = 84.49 (16)°]. The crystal packing is stabilized by intra­molecular and inter­molecular N—H⋯O hydrogen-bonding inter­actions. International Union of Crystallography 2012-09-15 /pmc/articles/PMC3470146/ /pubmed/23125590 http://dx.doi.org/10.1107/S1600536812038664 Text en © Tadjarodi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tadjarodi, Azadeh
Bijanzad, Keyvan
Notash, Behrouz
(Acetato-κ(2) O,O′)(acetato-κO)bis(2-amino-3-methyl­pyridine-κN (1))cobalt(II)
title (Acetato-κ(2) O,O′)(acetato-κO)bis(2-amino-3-methyl­pyridine-κN (1))cobalt(II)
title_full (Acetato-κ(2) O,O′)(acetato-κO)bis(2-amino-3-methyl­pyridine-κN (1))cobalt(II)
title_fullStr (Acetato-κ(2) O,O′)(acetato-κO)bis(2-amino-3-methyl­pyridine-κN (1))cobalt(II)
title_full_unstemmed (Acetato-κ(2) O,O′)(acetato-κO)bis(2-amino-3-methyl­pyridine-κN (1))cobalt(II)
title_short (Acetato-κ(2) O,O′)(acetato-κO)bis(2-amino-3-methyl­pyridine-κN (1))cobalt(II)
title_sort (acetato-κ(2) o,o′)(acetato-κo)bis(2-amino-3-methyl­pyridine-κn (1))cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470146/
https://www.ncbi.nlm.nih.gov/pubmed/23125590
http://dx.doi.org/10.1107/S1600536812038664
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