Bis(μ-4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κ(2) O:O′)bis[aqua(4,4′′-di­fluoro-1,1′:3′,1′′-terphenyl-2′-carboxyl­ato-κO)(pyridine-κN)cobalt(II)] diethyl ether disolvate

The structure of the title compound, [Co(2)(C(19)H(11)F(2)O(2))(4)(C(5)H(5)N)(2)(H(2)O)(2)]·2C(4)H(10)O, comprises two Co(II) atoms in a distorted square pyramidal coordination environment, straddling a crystallographic inversion center with a Co⋯Co separation of 3.1923 (15) Å. Each Co(2+) cation is...

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Autores principales: Kim, Namseok, Yoon, Yeahsel, Lee, Ha-Jin, Yoon, Sungho
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470148/
https://www.ncbi.nlm.nih.gov/pubmed/23125592
http://dx.doi.org/10.1107/S1600536812038391
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author Kim, Namseok
Yoon, Yeahsel
Lee, Ha-Jin
Yoon, Sungho
author_facet Kim, Namseok
Yoon, Yeahsel
Lee, Ha-Jin
Yoon, Sungho
author_sort Kim, Namseok
collection PubMed
description The structure of the title compound, [Co(2)(C(19)H(11)F(2)O(2))(4)(C(5)H(5)N)(2)(H(2)O)(2)]·2C(4)H(10)O, comprises two Co(II) atoms in a distorted square pyramidal coordination environment, straddling a crystallographic inversion center with a Co⋯Co separation of 3.1923 (15) Å. Each Co(2+) cation is coordinated by three O atoms of three 4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxyl­ate ligands, one water O atom and one pyridine N atom, forming a CoO(4)N polyhedron. Strong intra­molecular O—H⋯O hydrogen bonds are observed between terminal metal-bound carboxyl­ate groups and water O atoms.
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spelling pubmed-34701482012-11-02 Bis(μ-4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κ(2) O:O′)bis[aqua(4,4′′-di­fluoro-1,1′:3′,1′′-terphenyl-2′-carboxyl­ato-κO)(pyridine-κN)cobalt(II)] diethyl ether disolvate Kim, Namseok Yoon, Yeahsel Lee, Ha-Jin Yoon, Sungho Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, [Co(2)(C(19)H(11)F(2)O(2))(4)(C(5)H(5)N)(2)(H(2)O)(2)]·2C(4)H(10)O, comprises two Co(II) atoms in a distorted square pyramidal coordination environment, straddling a crystallographic inversion center with a Co⋯Co separation of 3.1923 (15) Å. Each Co(2+) cation is coordinated by three O atoms of three 4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxyl­ate ligands, one water O atom and one pyridine N atom, forming a CoO(4)N polyhedron. Strong intra­molecular O—H⋯O hydrogen bonds are observed between terminal metal-bound carboxyl­ate groups and water O atoms. International Union of Crystallography 2012-09-15 /pmc/articles/PMC3470148/ /pubmed/23125592 http://dx.doi.org/10.1107/S1600536812038391 Text en © Kim et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kim, Namseok
Yoon, Yeahsel
Lee, Ha-Jin
Yoon, Sungho
Bis(μ-4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κ(2) O:O′)bis[aqua(4,4′′-di­fluoro-1,1′:3′,1′′-terphenyl-2′-carboxyl­ato-κO)(pyridine-κN)cobalt(II)] diethyl ether disolvate
title Bis(μ-4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κ(2) O:O′)bis[aqua(4,4′′-di­fluoro-1,1′:3′,1′′-terphenyl-2′-carboxyl­ato-κO)(pyridine-κN)cobalt(II)] diethyl ether disolvate
title_full Bis(μ-4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κ(2) O:O′)bis[aqua(4,4′′-di­fluoro-1,1′:3′,1′′-terphenyl-2′-carboxyl­ato-κO)(pyridine-κN)cobalt(II)] diethyl ether disolvate
title_fullStr Bis(μ-4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κ(2) O:O′)bis[aqua(4,4′′-di­fluoro-1,1′:3′,1′′-terphenyl-2′-carboxyl­ato-κO)(pyridine-κN)cobalt(II)] diethyl ether disolvate
title_full_unstemmed Bis(μ-4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κ(2) O:O′)bis[aqua(4,4′′-di­fluoro-1,1′:3′,1′′-terphenyl-2′-carboxyl­ato-κO)(pyridine-κN)cobalt(II)] diethyl ether disolvate
title_short Bis(μ-4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κ(2) O:O′)bis[aqua(4,4′′-di­fluoro-1,1′:3′,1′′-terphenyl-2′-carboxyl­ato-κO)(pyridine-κN)cobalt(II)] diethyl ether disolvate
title_sort bis(μ-4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κ(2) o:o′)bis[aqua(4,4′′-di­fluoro-1,1′:3′,1′′-terphenyl-2′-carboxyl­ato-κo)(pyridine-κn)cobalt(ii)] diethyl ether disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470148/
https://www.ncbi.nlm.nih.gov/pubmed/23125592
http://dx.doi.org/10.1107/S1600536812038391
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