Bis[4-amino-3,5-bis­(pyridin-2-yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]diaqua­cobalt(II) bis­(perchlorate)

In the title structure, [Co(C(12)H(10)N(6))(2)(H(2)O)(2)](ClO(4))(2), the Co(II) atom lies on an inversion centre and is coordinated in a slightly distorted octa­hedral geometry by four N atoms from two 4-amino-3,5-bis­(pyridin-2-yl)-4H-1,2,4-triazole (adpt) ligands in equatorial positions and two O...

Descripción completa

Detalles Bibliográficos
Autores principales: Feng, Mi, Ji, Yu-Fei, Liang, Sheng-Li, Liu, Zhi-Liang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470152/
https://www.ncbi.nlm.nih.gov/pubmed/23125596
http://dx.doi.org/10.1107/S1600536812038573
_version_ 1782246206992285696
author Feng, Mi
Ji, Yu-Fei
Liang, Sheng-Li
Liu, Zhi-Liang
author_facet Feng, Mi
Ji, Yu-Fei
Liang, Sheng-Li
Liu, Zhi-Liang
author_sort Feng, Mi
collection PubMed
description In the title structure, [Co(C(12)H(10)N(6))(2)(H(2)O)(2)](ClO(4))(2), the Co(II) atom lies on an inversion centre and is coordinated in a slightly distorted octa­hedral geometry by four N atoms from two 4-amino-3,5-bis­(pyridin-2-yl)-4H-1,2,4-triazole (adpt) ligands in equatorial positions and two O atoms from two water mol­ecules in axial positions. An intra­molecular N—H⋯N inter­action stabilizes the mol­ecular conformation. Inter­molecular N—H⋯O and O—H⋯O inter­actions involving the perchlorate counter-anions extend the monomeric compound into a two-dimensional network parallel to the bc plane.
format Online
Article
Text
id pubmed-3470152
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-34701522012-11-02 Bis[4-amino-3,5-bis­(pyridin-2-yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]diaqua­cobalt(II) bis­(perchlorate) Feng, Mi Ji, Yu-Fei Liang, Sheng-Li Liu, Zhi-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title structure, [Co(C(12)H(10)N(6))(2)(H(2)O)(2)](ClO(4))(2), the Co(II) atom lies on an inversion centre and is coordinated in a slightly distorted octa­hedral geometry by four N atoms from two 4-amino-3,5-bis­(pyridin-2-yl)-4H-1,2,4-triazole (adpt) ligands in equatorial positions and two O atoms from two water mol­ecules in axial positions. An intra­molecular N—H⋯N inter­action stabilizes the mol­ecular conformation. Inter­molecular N—H⋯O and O—H⋯O inter­actions involving the perchlorate counter-anions extend the monomeric compound into a two-dimensional network parallel to the bc plane. International Union of Crystallography 2012-09-15 /pmc/articles/PMC3470152/ /pubmed/23125596 http://dx.doi.org/10.1107/S1600536812038573 Text en © Feng et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Feng, Mi
Ji, Yu-Fei
Liang, Sheng-Li
Liu, Zhi-Liang
Bis[4-amino-3,5-bis­(pyridin-2-yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]diaqua­cobalt(II) bis­(perchlorate)
title Bis[4-amino-3,5-bis­(pyridin-2-yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]diaqua­cobalt(II) bis­(perchlorate)
title_full Bis[4-amino-3,5-bis­(pyridin-2-yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]diaqua­cobalt(II) bis­(perchlorate)
title_fullStr Bis[4-amino-3,5-bis­(pyridin-2-yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]diaqua­cobalt(II) bis­(perchlorate)
title_full_unstemmed Bis[4-amino-3,5-bis­(pyridin-2-yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]diaqua­cobalt(II) bis­(perchlorate)
title_short Bis[4-amino-3,5-bis­(pyridin-2-yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]diaqua­cobalt(II) bis­(perchlorate)
title_sort bis[4-amino-3,5-bis­(pyridin-2-yl)-4h-1,2,4-triazole-κ(2) n (1),n (5)]diaqua­cobalt(ii) bis­(perchlorate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470152/
https://www.ncbi.nlm.nih.gov/pubmed/23125596
http://dx.doi.org/10.1107/S1600536812038573
work_keys_str_mv AT fengmi bis4amino35bispyridin2yl4h124triazolek2n1n5diaquacobaltiibisperchlorate
AT jiyufei bis4amino35bispyridin2yl4h124triazolek2n1n5diaquacobaltiibisperchlorate
AT liangshengli bis4amino35bispyridin2yl4h124triazolek2n1n5diaquacobaltiibisperchlorate
AT liuzhiliang bis4amino35bispyridin2yl4h124triazolek2n1n5diaquacobaltiibisperchlorate

Ejemplares similares