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3-(Ferrocen-1-ylcarbonyl)-1-methyl-4-(4-methylphenyl)spiro[pyrrolidine-2,11′-indeno[1,2-b]quinoxaline]
In the title compound, [Fe(C(5)H(5))(C(32)H(26)N(3)O)], the pyrrolidine ring adopts a twist conformation. The indeno–quinoxaline ring system [86.44 (5)°], the methylphenyl ring [86.06 (7)°] and the ferrocene rings [82.00 (7) and 83.95 (9)°] are almost perpendicular to the pyrrolidine ring. The two...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470153/ https://www.ncbi.nlm.nih.gov/pubmed/23125597 http://dx.doi.org/10.1107/S1600536812036951 |
| _version_ | 1782246207218778112 |
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| author | Vijayakumar, B. Gavaskar, D. Srinivasan, T. Raghunathan, R. Velmurugan, D. |
| author_facet | Vijayakumar, B. Gavaskar, D. Srinivasan, T. Raghunathan, R. Velmurugan, D. |
| author_sort | Vijayakumar, B. |
| collection | PubMed |
| description | In the title compound, [Fe(C(5)H(5))(C(32)H(26)N(3)O)], the pyrrolidine ring adopts a twist conformation. The indeno–quinoxaline ring system [86.44 (5)°], the methylphenyl ring [86.06 (7)°] and the ferrocene rings [82.00 (7) and 83.95 (9)°] are almost perpendicular to the pyrrolidine ring. The two cyclopentadienyl rings adopt an eclipsed conformation. The crystal structure features C—H⋯N interactions. |
| format | Online Article Text |
| id | pubmed-3470153 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-34701532012-11-02 3-(Ferrocen-1-ylcarbonyl)-1-methyl-4-(4-methylphenyl)spiro[pyrrolidine-2,11′-indeno[1,2-b]quinoxaline] Vijayakumar, B. Gavaskar, D. Srinivasan, T. Raghunathan, R. Velmurugan, D. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(C(5)H(5))(C(32)H(26)N(3)O)], the pyrrolidine ring adopts a twist conformation. The indeno–quinoxaline ring system [86.44 (5)°], the methylphenyl ring [86.06 (7)°] and the ferrocene rings [82.00 (7) and 83.95 (9)°] are almost perpendicular to the pyrrolidine ring. The two cyclopentadienyl rings adopt an eclipsed conformation. The crystal structure features C—H⋯N interactions. International Union of Crystallography 2012-09-15 /pmc/articles/PMC3470153/ /pubmed/23125597 http://dx.doi.org/10.1107/S1600536812036951 Text en © Vijayakumar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Vijayakumar, B. Gavaskar, D. Srinivasan, T. Raghunathan, R. Velmurugan, D. 3-(Ferrocen-1-ylcarbonyl)-1-methyl-4-(4-methylphenyl)spiro[pyrrolidine-2,11′-indeno[1,2-b]quinoxaline] |
| title | 3-(Ferrocen-1-ylcarbonyl)-1-methyl-4-(4-methylphenyl)spiro[pyrrolidine-2,11′-indeno[1,2-b]quinoxaline] |
| title_full | 3-(Ferrocen-1-ylcarbonyl)-1-methyl-4-(4-methylphenyl)spiro[pyrrolidine-2,11′-indeno[1,2-b]quinoxaline] |
| title_fullStr | 3-(Ferrocen-1-ylcarbonyl)-1-methyl-4-(4-methylphenyl)spiro[pyrrolidine-2,11′-indeno[1,2-b]quinoxaline] |
| title_full_unstemmed | 3-(Ferrocen-1-ylcarbonyl)-1-methyl-4-(4-methylphenyl)spiro[pyrrolidine-2,11′-indeno[1,2-b]quinoxaline] |
| title_short | 3-(Ferrocen-1-ylcarbonyl)-1-methyl-4-(4-methylphenyl)spiro[pyrrolidine-2,11′-indeno[1,2-b]quinoxaline] |
| title_sort | 3-(ferrocen-1-ylcarbonyl)-1-methyl-4-(4-methylphenyl)spiro[pyrrolidine-2,11′-indeno[1,2-b]quinoxaline] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470153/ https://www.ncbi.nlm.nih.gov/pubmed/23125597 http://dx.doi.org/10.1107/S1600536812036951 |
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