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(μ-3,5,9,11-Tetra­oxo-4,10-diaza­tetra­cyclo­[5.5.2.0(2,6).0(8,12)]tetra­dec-13-ene-4,10-diido-κ(2) N:N′)bis­[(2,2′-bipyridine-κ(2) N,N′)silver(I)] dihydrate

In the title complex, [Ag(2)(C(12)H(8)N(2)O(4))(C(10)H(8)N(2))(2)]·2H(2)O, the Ag(I) ion is three-coordinated by two N atoms from a chelating 2,2′-bipyridine ligand and one N atom from an imide ligand in a Y-shaped fashion. The imide ligand and the complex lie on a twofold rotation axis. The ligand...

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Detalles Bibliográficos
Autor principal: Zhang, Yongmei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470154/
https://www.ncbi.nlm.nih.gov/pubmed/23125598
http://dx.doi.org/10.1107/S1600536812038640
Descripción
Sumario:In the title complex, [Ag(2)(C(12)H(8)N(2)O(4))(C(10)H(8)N(2))(2)]·2H(2)O, the Ag(I) ion is three-coordinated by two N atoms from a chelating 2,2′-bipyridine ligand and one N atom from an imide ligand in a Y-shaped fashion. The imide ligand and the complex lie on a twofold rotation axis. The ligand bridges two Ag(I) ions, forming a dinuclear complex. In the crystal, O—H⋯O hydrogen bonds link the lattice water mol­ecules and the complex mol­ecules into a ribbon-like structure along [001]. π–π inter­actions are observed between the pyridine rings [centroid–centroid distance = 3.8289 (14) Å].