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(μ-3,5,9,11-Tetraoxo-4,10-diazatetracyclo[5.5.2.0(2,6).0(8,12)]tetradec-13-ene-4,10-diido-κ(2) N:N′)bis[(2,2′-bipyridine-κ(2) N,N′)silver(I)] dihydrate
In the title complex, [Ag(2)(C(12)H(8)N(2)O(4))(C(10)H(8)N(2))(2)]·2H(2)O, the Ag(I) ion is three-coordinated by two N atoms from a chelating 2,2′-bipyridine ligand and one N atom from an imide ligand in a Y-shaped fashion. The imide ligand and the complex lie on a twofold rotation axis. The ligand...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470154/ https://www.ncbi.nlm.nih.gov/pubmed/23125598 http://dx.doi.org/10.1107/S1600536812038640 |
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author | Zhang, Yongmei |
author_facet | Zhang, Yongmei |
author_sort | Zhang, Yongmei |
collection | PubMed |
description | In the title complex, [Ag(2)(C(12)H(8)N(2)O(4))(C(10)H(8)N(2))(2)]·2H(2)O, the Ag(I) ion is three-coordinated by two N atoms from a chelating 2,2′-bipyridine ligand and one N atom from an imide ligand in a Y-shaped fashion. The imide ligand and the complex lie on a twofold rotation axis. The ligand bridges two Ag(I) ions, forming a dinuclear complex. In the crystal, O—H⋯O hydrogen bonds link the lattice water molecules and the complex molecules into a ribbon-like structure along [001]. π–π interactions are observed between the pyridine rings [centroid–centroid distance = 3.8289 (14) Å]. |
format | Online Article Text |
id | pubmed-3470154 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34701542012-11-02 (μ-3,5,9,11-Tetraoxo-4,10-diazatetracyclo[5.5.2.0(2,6).0(8,12)]tetradec-13-ene-4,10-diido-κ(2) N:N′)bis[(2,2′-bipyridine-κ(2) N,N′)silver(I)] dihydrate Zhang, Yongmei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ag(2)(C(12)H(8)N(2)O(4))(C(10)H(8)N(2))(2)]·2H(2)O, the Ag(I) ion is three-coordinated by two N atoms from a chelating 2,2′-bipyridine ligand and one N atom from an imide ligand in a Y-shaped fashion. The imide ligand and the complex lie on a twofold rotation axis. The ligand bridges two Ag(I) ions, forming a dinuclear complex. In the crystal, O—H⋯O hydrogen bonds link the lattice water molecules and the complex molecules into a ribbon-like structure along [001]. π–π interactions are observed between the pyridine rings [centroid–centroid distance = 3.8289 (14) Å]. International Union of Crystallography 2012-09-15 /pmc/articles/PMC3470154/ /pubmed/23125598 http://dx.doi.org/10.1107/S1600536812038640 Text en © Yongmei Zhang 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhang, Yongmei (μ-3,5,9,11-Tetraoxo-4,10-diazatetracyclo[5.5.2.0(2,6).0(8,12)]tetradec-13-ene-4,10-diido-κ(2) N:N′)bis[(2,2′-bipyridine-κ(2) N,N′)silver(I)] dihydrate |
title | (μ-3,5,9,11-Tetraoxo-4,10-diazatetracyclo[5.5.2.0(2,6).0(8,12)]tetradec-13-ene-4,10-diido-κ(2)
N:N′)bis[(2,2′-bipyridine-κ(2)
N,N′)silver(I)] dihydrate |
title_full | (μ-3,5,9,11-Tetraoxo-4,10-diazatetracyclo[5.5.2.0(2,6).0(8,12)]tetradec-13-ene-4,10-diido-κ(2)
N:N′)bis[(2,2′-bipyridine-κ(2)
N,N′)silver(I)] dihydrate |
title_fullStr | (μ-3,5,9,11-Tetraoxo-4,10-diazatetracyclo[5.5.2.0(2,6).0(8,12)]tetradec-13-ene-4,10-diido-κ(2)
N:N′)bis[(2,2′-bipyridine-κ(2)
N,N′)silver(I)] dihydrate |
title_full_unstemmed | (μ-3,5,9,11-Tetraoxo-4,10-diazatetracyclo[5.5.2.0(2,6).0(8,12)]tetradec-13-ene-4,10-diido-κ(2)
N:N′)bis[(2,2′-bipyridine-κ(2)
N,N′)silver(I)] dihydrate |
title_short | (μ-3,5,9,11-Tetraoxo-4,10-diazatetracyclo[5.5.2.0(2,6).0(8,12)]tetradec-13-ene-4,10-diido-κ(2)
N:N′)bis[(2,2′-bipyridine-κ(2)
N,N′)silver(I)] dihydrate |
title_sort | (μ-3,5,9,11-tetraoxo-4,10-diazatetracyclo[5.5.2.0(2,6).0(8,12)]tetradec-13-ene-4,10-diido-κ(2)
n:n′)bis[(2,2′-bipyridine-κ(2)
n,n′)silver(i)] dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470154/ https://www.ncbi.nlm.nih.gov/pubmed/23125598 http://dx.doi.org/10.1107/S1600536812038640 |
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