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(μ-3,5,9,11-Tetra­oxo-4,10-diaza­tetra­cyclo­[5.5.2.0(2,6).0(8,12)]tetra­dec-13-ene-4,10-diido-κ(2) N:N′)bis­[(2,2′-bipyridine-κ(2) N,N′)silver(I)] dihydrate

In the title complex, [Ag(2)(C(12)H(8)N(2)O(4))(C(10)H(8)N(2))(2)]·2H(2)O, the Ag(I) ion is three-coordinated by two N atoms from a chelating 2,2′-bipyridine ligand and one N atom from an imide ligand in a Y-shaped fashion. The imide ligand and the complex lie on a twofold rotation axis. The ligand...

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Autor principal: Zhang, Yongmei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470154/
https://www.ncbi.nlm.nih.gov/pubmed/23125598
http://dx.doi.org/10.1107/S1600536812038640
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author Zhang, Yongmei
author_facet Zhang, Yongmei
author_sort Zhang, Yongmei
collection PubMed
description In the title complex, [Ag(2)(C(12)H(8)N(2)O(4))(C(10)H(8)N(2))(2)]·2H(2)O, the Ag(I) ion is three-coordinated by two N atoms from a chelating 2,2′-bipyridine ligand and one N atom from an imide ligand in a Y-shaped fashion. The imide ligand and the complex lie on a twofold rotation axis. The ligand bridges two Ag(I) ions, forming a dinuclear complex. In the crystal, O—H⋯O hydrogen bonds link the lattice water mol­ecules and the complex mol­ecules into a ribbon-like structure along [001]. π–π inter­actions are observed between the pyridine rings [centroid–centroid distance = 3.8289 (14) Å].
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spelling pubmed-34701542012-11-02 (μ-3,5,9,11-Tetra­oxo-4,10-diaza­tetra­cyclo­[5.5.2.0(2,6).0(8,12)]tetra­dec-13-ene-4,10-diido-κ(2) N:N′)bis­[(2,2′-bipyridine-κ(2) N,N′)silver(I)] dihydrate Zhang, Yongmei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ag(2)(C(12)H(8)N(2)O(4))(C(10)H(8)N(2))(2)]·2H(2)O, the Ag(I) ion is three-coordinated by two N atoms from a chelating 2,2′-bipyridine ligand and one N atom from an imide ligand in a Y-shaped fashion. The imide ligand and the complex lie on a twofold rotation axis. The ligand bridges two Ag(I) ions, forming a dinuclear complex. In the crystal, O—H⋯O hydrogen bonds link the lattice water mol­ecules and the complex mol­ecules into a ribbon-like structure along [001]. π–π inter­actions are observed between the pyridine rings [centroid–centroid distance = 3.8289 (14) Å]. International Union of Crystallography 2012-09-15 /pmc/articles/PMC3470154/ /pubmed/23125598 http://dx.doi.org/10.1107/S1600536812038640 Text en © Yongmei Zhang 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Yongmei
(μ-3,5,9,11-Tetra­oxo-4,10-diaza­tetra­cyclo­[5.5.2.0(2,6).0(8,12)]tetra­dec-13-ene-4,10-diido-κ(2) N:N′)bis­[(2,2′-bipyridine-κ(2) N,N′)silver(I)] dihydrate
title (μ-3,5,9,11-Tetra­oxo-4,10-diaza­tetra­cyclo­[5.5.2.0(2,6).0(8,12)]tetra­dec-13-ene-4,10-diido-κ(2) N:N′)bis­[(2,2′-bipyridine-κ(2) N,N′)silver(I)] dihydrate
title_full (μ-3,5,9,11-Tetra­oxo-4,10-diaza­tetra­cyclo­[5.5.2.0(2,6).0(8,12)]tetra­dec-13-ene-4,10-diido-κ(2) N:N′)bis­[(2,2′-bipyridine-κ(2) N,N′)silver(I)] dihydrate
title_fullStr (μ-3,5,9,11-Tetra­oxo-4,10-diaza­tetra­cyclo­[5.5.2.0(2,6).0(8,12)]tetra­dec-13-ene-4,10-diido-κ(2) N:N′)bis­[(2,2′-bipyridine-κ(2) N,N′)silver(I)] dihydrate
title_full_unstemmed (μ-3,5,9,11-Tetra­oxo-4,10-diaza­tetra­cyclo­[5.5.2.0(2,6).0(8,12)]tetra­dec-13-ene-4,10-diido-κ(2) N:N′)bis­[(2,2′-bipyridine-κ(2) N,N′)silver(I)] dihydrate
title_short (μ-3,5,9,11-Tetra­oxo-4,10-diaza­tetra­cyclo­[5.5.2.0(2,6).0(8,12)]tetra­dec-13-ene-4,10-diido-κ(2) N:N′)bis­[(2,2′-bipyridine-κ(2) N,N′)silver(I)] dihydrate
title_sort (μ-3,5,9,11-tetra­oxo-4,10-diaza­tetra­cyclo­[5.5.2.0(2,6).0(8,12)]tetra­dec-13-ene-4,10-diido-κ(2) n:n′)bis­[(2,2′-bipyridine-κ(2) n,n′)silver(i)] dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470154/
https://www.ncbi.nlm.nih.gov/pubmed/23125598
http://dx.doi.org/10.1107/S1600536812038640
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