Poly[(μ(4)-biphenyl-2,4′-dicarboxyl­ato-κ(5)O(2):O(2′):O(4):O(4),O(4′))zinc]

The crystal structure of the polymeric title complex, [Zn(C(14)H(8)O(4))](n), is composed of layers parallel to (110) formed by linking of Zn–carboxyl­ate chains with biphenyl units of the biphenyl-2,4′-dicarboxyl­ate (bpdc) ligands. The Zn(II) atom is five-coordinated in a distorted square-pyramida...

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Detalles Bibliográficos
Autor principal: Tian, Yu-Guang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470155/
https://www.ncbi.nlm.nih.gov/pubmed/23125599
http://dx.doi.org/10.1107/S1600536812038901
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author Tian, Yu-Guang
author_facet Tian, Yu-Guang
author_sort Tian, Yu-Guang
collection PubMed
description The crystal structure of the polymeric title complex, [Zn(C(14)H(8)O(4))](n), is composed of layers parallel to (110) formed by linking of Zn–carboxyl­ate chains with biphenyl units of the biphenyl-2,4′-dicarboxyl­ate (bpdc) ligands. The Zn(II) atom is five-coordinated in a distorted square-pyramidal geometry by five O atoms from four bpdc ligands. The dihedral angle between the benzene rings is 52.32 (12)°.
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spelling pubmed-34701552012-11-02 Poly[(μ(4)-biphenyl-2,4′-dicarboxyl­ato-κ(5)O(2):O(2′):O(4):O(4),O(4′))zinc] Tian, Yu-Guang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the polymeric title complex, [Zn(C(14)H(8)O(4))](n), is composed of layers parallel to (110) formed by linking of Zn–carboxyl­ate chains with biphenyl units of the biphenyl-2,4′-dicarboxyl­ate (bpdc) ligands. The Zn(II) atom is five-coordinated in a distorted square-pyramidal geometry by five O atoms from four bpdc ligands. The dihedral angle between the benzene rings is 52.32 (12)°. International Union of Crystallography 2012-09-19 /pmc/articles/PMC3470155/ /pubmed/23125599 http://dx.doi.org/10.1107/S1600536812038901 Text en © Yu-Guang Tian 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tian, Yu-Guang
Poly[(μ(4)-biphenyl-2,4′-dicarboxyl­ato-κ(5)O(2):O(2′):O(4):O(4),O(4′))zinc]
title Poly[(μ(4)-biphenyl-2,4′-dicarboxyl­ato-κ(5)O(2):O(2′):O(4):O(4),O(4′))zinc]
title_full Poly[(μ(4)-biphenyl-2,4′-dicarboxyl­ato-κ(5)O(2):O(2′):O(4):O(4),O(4′))zinc]
title_fullStr Poly[(μ(4)-biphenyl-2,4′-dicarboxyl­ato-κ(5)O(2):O(2′):O(4):O(4),O(4′))zinc]
title_full_unstemmed Poly[(μ(4)-biphenyl-2,4′-dicarboxyl­ato-κ(5)O(2):O(2′):O(4):O(4),O(4′))zinc]
title_short Poly[(μ(4)-biphenyl-2,4′-dicarboxyl­ato-κ(5)O(2):O(2′):O(4):O(4),O(4′))zinc]
title_sort poly[(μ(4)-biphenyl-2,4′-dicarboxyl­ato-κ(5)o(2):o(2′):o(4):o(4),o(4′))zinc]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470155/
https://www.ncbi.nlm.nih.gov/pubmed/23125599
http://dx.doi.org/10.1107/S1600536812038901
work_keys_str_mv AT tianyuguang polym4biphenyl24dicarboxylatok5o2o2o4o4o4zinc

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