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{2,6-Bis[(2,6-diisopropylphosphanyl)oxy]-4-fluorophenyl-κ(3) P,C (1),P′}(1H-pyrazole-κN (2))nickel(II) hexafluorophosphate
The title compound, [Ni(C(18)H(30)FO(2)P(2))(C(3)H(4)N(2))]PF(6), was prepared by halide abstraction with TlPF(6) in the presence of CH(3)CN in CDCl(3) from the respective neutral pincer chlorido analogue followed by addition of pyrazole. The PO—C—OP pincer ligand acts in typical trans-P(2) tridenta...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470159/ https://www.ncbi.nlm.nih.gov/pubmed/23125603 http://dx.doi.org/10.1107/S1600536812039207 |