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Poly[diaqua­[μ-1,4-bis­(1H-imidazol-1-yl)benzene-κ(2) N (3):N (3′)](μ-fumarato-κ(2) O (1):O (4))nickel(II)]

In the title compound, [Ni(C(4)H(2)O(4))(C(12)H(10)N(4))(H(2)O)(2)](n), the Ni(II) ion has a distorted octa­hedral coordination geometry. The asymmetric unit is composed of an Ni(2+) ion, located on a twofold rotation axis, one half of a 1,4-bis­(1H-imidazol-1-yl)benzene (BIMB) ligand and one half o...

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Detalles Bibliográficos
Autores principales: Bian, Chang-Xin, Yao, Xiao-Qiang, Song, Yu-Min
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470161/
https://www.ncbi.nlm.nih.gov/pubmed/23125605
http://dx.doi.org/10.1107/S1600536812038895
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author Bian, Chang-Xin
Yao, Xiao-Qiang
Song, Yu-Min
author_facet Bian, Chang-Xin
Yao, Xiao-Qiang
Song, Yu-Min
author_sort Bian, Chang-Xin
collection PubMed
description In the title compound, [Ni(C(4)H(2)O(4))(C(12)H(10)N(4))(H(2)O)(2)](n), the Ni(II) ion has a distorted octa­hedral coordination geometry. The asymmetric unit is composed of an Ni(2+) ion, located on a twofold rotation axis, one half of a 1,4-bis­(1H-imidazol-1-yl)benzene (BIMB) ligand and one half of a fumarte (fum(2−)) dianion, both ligands being located about inversion centers, and a coordinating water mol­ecule. The Ni(II) ions are linked by two BIMB ligands and two fum(2−) dianions, forming a four-connected layered structure parallel to (010) with a 4(4)-sql topology. Within each layer, there are rhombic grids with dimensions of ca 13.5 × 9.0 Å and approximate angles of 109 and 70°. The crystal packing features a two-dimensional → two-dimensional parallel/parallel interpenetration in which one undulating layer is catenated to another equivalent one, forming a new bilayer. Moreover, the entangled two-dimensional layers are connected by O—H⋯O and C—H⋯O hydrogen bonds, generating a three-dimensional structure.
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spelling pubmed-34701612012-11-02 Poly[diaqua­[μ-1,4-bis­(1H-imidazol-1-yl)benzene-κ(2) N (3):N (3′)](μ-fumarato-κ(2) O (1):O (4))nickel(II)] Bian, Chang-Xin Yao, Xiao-Qiang Song, Yu-Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(4)H(2)O(4))(C(12)H(10)N(4))(H(2)O)(2)](n), the Ni(II) ion has a distorted octa­hedral coordination geometry. The asymmetric unit is composed of an Ni(2+) ion, located on a twofold rotation axis, one half of a 1,4-bis­(1H-imidazol-1-yl)benzene (BIMB) ligand and one half of a fumarte (fum(2−)) dianion, both ligands being located about inversion centers, and a coordinating water mol­ecule. The Ni(II) ions are linked by two BIMB ligands and two fum(2−) dianions, forming a four-connected layered structure parallel to (010) with a 4(4)-sql topology. Within each layer, there are rhombic grids with dimensions of ca 13.5 × 9.0 Å and approximate angles of 109 and 70°. The crystal packing features a two-dimensional → two-dimensional parallel/parallel interpenetration in which one undulating layer is catenated to another equivalent one, forming a new bilayer. Moreover, the entangled two-dimensional layers are connected by O—H⋯O and C—H⋯O hydrogen bonds, generating a three-dimensional structure. International Union of Crystallography 2012-09-22 /pmc/articles/PMC3470161/ /pubmed/23125605 http://dx.doi.org/10.1107/S1600536812038895 Text en © Bian et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bian, Chang-Xin
Yao, Xiao-Qiang
Song, Yu-Min
Poly[diaqua­[μ-1,4-bis­(1H-imidazol-1-yl)benzene-κ(2) N (3):N (3′)](μ-fumarato-κ(2) O (1):O (4))nickel(II)]
title Poly[diaqua­[μ-1,4-bis­(1H-imidazol-1-yl)benzene-κ(2) N (3):N (3′)](μ-fumarato-κ(2) O (1):O (4))nickel(II)]
title_full Poly[diaqua­[μ-1,4-bis­(1H-imidazol-1-yl)benzene-κ(2) N (3):N (3′)](μ-fumarato-κ(2) O (1):O (4))nickel(II)]
title_fullStr Poly[diaqua­[μ-1,4-bis­(1H-imidazol-1-yl)benzene-κ(2) N (3):N (3′)](μ-fumarato-κ(2) O (1):O (4))nickel(II)]
title_full_unstemmed Poly[diaqua­[μ-1,4-bis­(1H-imidazol-1-yl)benzene-κ(2) N (3):N (3′)](μ-fumarato-κ(2) O (1):O (4))nickel(II)]
title_short Poly[diaqua­[μ-1,4-bis­(1H-imidazol-1-yl)benzene-κ(2) N (3):N (3′)](μ-fumarato-κ(2) O (1):O (4))nickel(II)]
title_sort poly[diaqua­[μ-1,4-bis­(1h-imidazol-1-yl)benzene-κ(2) n (3):n (3′)](μ-fumarato-κ(2) o (1):o (4))nickel(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470161/
https://www.ncbi.nlm.nih.gov/pubmed/23125605
http://dx.doi.org/10.1107/S1600536812038895
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