Bis(1H-benzimidazole-2-carboxyl­ato-κ(2) N (3),O)bis­(ethanol-κO)manganese(II)

In the title compound, [Mn(C(8)H(5)N(2)O(2))(2)(C(2)H(5)OH)(2)], the Mn(II) atom is six-coordinated by two N and two O atoms from two 1H-benzimidazole-2-carboxyl­ate (L) ligands and by two O atoms from two ethanol mol­ecules in a distorted octa­hedral geometry. The mean planes of the two L ligands a...

Descripción completa

Detalles Bibliográficos
Autores principales: Nie, Jian-Hua, Lin, Yue-Hua, Xu, Chun-Tao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470162/
https://www.ncbi.nlm.nih.gov/pubmed/23125606
http://dx.doi.org/10.1107/S1600536812039475
Descripción
Sumario:In the title compound, [Mn(C(8)H(5)N(2)O(2))(2)(C(2)H(5)OH)(2)], the Mn(II) atom is six-coordinated by two N and two O atoms from two 1H-benzimidazole-2-carboxyl­ate (L) ligands and by two O atoms from two ethanol mol­ecules in a distorted octa­hedral geometry. The mean planes of the two L ligands are inclined to each other at 7.6 (1)°. In the crystal, N—H⋯O and O—H⋯O hydrogen bonds link the mol­ecules into layers parallel to the ab plane.

Ejemplares similares